Radical polymerization of acrylic monomers: An overview

N Ballard, JM Asua - Progress in Polymer Science, 2018 - Elsevier
Since their discovery and development in the 20th century, acrylic polymers have become
an integral part of numerous industries and are used in a myriad of applications. As is true …

Radical polymerization of acrylates, methacrylates, and styrene: Biobased approaches, mechanism, kinetics, secondary reactions, and modeling

T Pirman, M Ocepek, B Likozar - Industrial & Engineering …, 2021 - ACS Publications
Biobased polymer molecules are a goal for the future. Here, the different intermediate
pathways toward renewable structural constituents, which can substitute petrochemically …

A novel self-degradable gel (SDG) as liquid temporary plugging agent for high-temperature reservoirs

C Zou, C Dai, Y Liu, Q You, F Ding, Y Huang… - Journal of Molecular …, 2023 - Elsevier
In recent years, the liquid temporary plugging agent has drawn extensive attention,
especially in the repeated fracturing operation for stimulating unconventional oil and gas …

Polymerization reactor modeling in industry

PA Mueller, JR Richards… - Macromolecular Reaction …, 2011 - Wiley Online Library
This paper provides an industrial perspective for the development of polymer reaction
engineering models and their application to create new materials, products, and improved or …

Impact of side reactions on molar mass distribution, unsaturation level and branching density in solution free radical polymerization of n-butyl acrylate under well …

M Edeleva, YW Marien, PHM Van Steenberge… - Polymer …, 2021 - pubs.rsc.org
The radical chemistry of polyacrylate synthesis is non-trivial, due to a significant amount of
side reactions. Backbiting transforms conventional secondary end-chain radicals (ECRs) in …

Jacket temperature regulation allowing well-defined non-adiabatic lab-scale solution free radical polymerization of acrylates

M Edeleva, YW Marien… - Reaction Chemistry & …, 2021 - pubs.rsc.org
Conventional batch solution free radical polymerization (FRP) of n-butyl acrylate (nBuA) with
thermal initiators such as 2, 2′-azobis (2-methylpropionitrile)(AIBN) is known to be strongly …

From n-butyl acrylate Arrhenius parameters for backbiting and tertiary propagation to β-scission via stepwise pulsed laser polymerization

AB Vir, YW Marien, PHM Van Steenberge… - Polymer …, 2019 - pubs.rsc.org
Arrhenius parameters for backbiting (bb), mid-chain radical propagation (pm) and β-scission
in n-butyl acrylate radical polymerization are determined based on pulsed laser …

Disproportionation or combination? The termination of acrylate radicals in ATRP

TG Ribelli, KF Augustine, M Fantin, P Krys, R Poli… - …, 2017 - ACS Publications
The termination of acrylate radicals in atom transfer radical polymerization (ATRP) can
involve either conventional bimolecular radical termination (RT) or catalytic radical …

Deterministic modeling of non-adiabatic solution radical polymerization of n-butyl acrylate in light of runaway prevention

YN Yang, CX Zhu, YN Zhou, ZH Luo - Chemical Engineering Journal, 2022 - Elsevier
Acrylate polymerizations with high exothermicity exhibit strongly non-isothermal
characteristics. The presence of side reactions involved in the polymerization mechanisms …

Kinetic Monte Carlo modeling extracts information on chain initiation and termination from complete PLP-SEC traces

YW Marien, PHM Van Steenberge… - …, 2017 - ACS Publications
Complete pulsed laser polymerization (PLP) log-molar mass distributions (log-MMDs) are
accurately simulated using kinetic Monte Carlo (k MC) modeling to gain not only knowledge …