Corroles are synthetic porphyrin analogs that contain one meso carbon atom lesser and
bear a trianionic N4 metal-chelating core. They require in-depth preparative chemistry …

Metal complexes of multi‐porphyrins and multi‐corroles are unique systems that display a
host of extremely interesting properties. Availability of free meso and β positions allow …

Considering the overwhelming importance and involvement of iron in numerous biocatalytic
processes, the scarceness of synthetic iron complexes as water oxidation catalysts (WOCs) …

We report a systematic investigation of a series of Ag (II) and Ag (III) complexes of porphyrins
and their analogues using UV–vis magnetic circular dichroism (MCD) spectroscopies and …

de Visser et al. demonstrated theoretically that although vanadium (IV)-oxo complexes are
slow oxidants, in the presence of H2O2 they generated a side-on vanadium-peroxo …

For the first-row middle transition metals (Cr, Mn, and Fe), the formal oxidation states are
relatively lower. However, biological systems in various enzymatic reactions rely extensively …

A new method of activating corrole macrocycles via an in situ generated SCN radical has
been developed at very mild conditions at room temperature. This photoredox reaction …

Metallophilic interactions between closed-shell metal centers are exemplified by d10 ions,
with Au (I) aurophilic interactions as the archetype. Such an interaction extends to d8 …

In ample variety of transformations, the presence of silver as an additive or co‐catalyst is
believed to be innocuous for the efficiency of the operating metal catalyst. Even though Ag …

Sharpless et al. have described, while performing the molybdenum-catalyzed epoxidation
reaction of olefins using alkyl hydroperoxides, that the molybdenum-oxo moiety is an active …