The halogen-atom transfer (XAT) is one of the most important and applied processes for the
generation of carbon radicals in synthetic chemistry. In this review, we summarize and …

This Perspective illustrates the defining characteristics of free radical chemistry, beginning
with its rich and storied history. Studies from our laboratory are discussed along with recent …

A useful protocol for achieving decarboxylative cross-coupling (DCC) of redox-active esters
(RAE, isolated or generated in situ) and halo (hetero) arenes is reported. This pragmatically …

The selective functionalization of remote C–H bonds via intramolecular hydrogen atom
transfer (HAT) is transformative for organic synthesis. This radical-mediated strategy …

Cascade radical cyclization is an attractive synthetic method due to its high atom-and step-
economy to construct carbo-and heterocycles, which have wide applications in chemical …

1. INTRODUCTION “Cascade” radical reactions, also known as “tandem” or “domino” radical
reactions, are characterized by the fact that they proceed through two or more consecutive …

The use of radicals1 in organic synthesis has increased dramatically within the last decade.
At the beginning of the 1980's, the place of radical reactions in natural products total …

Synthetic organic chemistry has been strongly influenced over the past 20 years by the
explosion of two main areas of research, namely: transition metal-mediated synthetic …

A radical-mediated strategy for β C–H amination of alcohols has been developed. This
approach employs a radical relay chaperone, which serves as a traceless director that …

Detailing commonly used methods and procedures, this reference discusses the reactions
and derivative forms of carbohydrates. Preparative Carbohydrate Chemistry covers the …