Low‐cost and resourceful transition metal phosphides (TMPs) have gradually received wide
acceptance in the energy industry through exhibiting comparable catalytic activity and long …

Activation of dinitrogen plays an important role in daily anthropogenic life, and the processes
by which this fixation occurs have been a longstanding and significant research focus within …

The unexpectedly facile insertion of Rh or Ir into a B–Ph bond (reversible for Rh) converts a
borane/bis (phosphine) precursor into a boryl/bis (phosphine) PBP pincer ligand …

Conspectus Nickel pincer systems have recently attracted much attention for applications in
various organometallic reactions and catalysis involving small molecule activation. Their …

The synthesis and reactivity of an ambiphilic iridium complex IrCl (PPh3)(L1)(1; L1= P (N
(oN (2-pyridyl) C6H4) 2)) featuring a chelating nontrigonal phosphorus triamide ligand is …

The synthesis and characterization of (tBuPBP) Ni (OAc)(5) by insertion of carbon dioxide
into the Ni− C bond of (tBuPBP) NiMe (1) is presented. An unexpected CO2 cleavage …

The insertion of carbon dioxide into metal element σ-bonds is an important elementary step
in many catalytic reactions for carbon dioxide valorization. Here, the insertion of carbon …

Addition of H2 across the cobalt–phosphorus bond of (PPP) CoPMe3 (3) is demonstrated,
where PPP is a monoanionic diphosphine pincer ligand with a central N‐heterocyclic …

Conspectus Carbon dioxide conversion mediated by transition metal complexes continues
to attract much attention because of its future potential utilization as a nontoxic and …

While organoboron compound is one of the most attractive and widely used nucleophiles in
transition-metal-catalyzed coupling processes, they require sacrificial reagents for …