Metal–organic network-forming glasses

N Ma, S Horike - Chemical Reviews, 2022 - ACS Publications
The crystal–liquid–glass phase transition of coordination polymers (CPs) and metal–organic
frameworks (MOFs) offers attractive opportunities as a new class of amorphous materials …

Assembling metal–organic cages as porous materials

E Sánchez-González, MY Tsang, J Troyano… - Chemical Society …, 2022 - pubs.rsc.org
There is growing interest in metal–organic cages (MOCs) as porous materials owing to their
processability in solution. The discrete molecular character and surface features of MOCs …

Hierarchical porous metal–organic gels and derived materials: from fundamentals to potential applications

JK Wychowaniec, H Saini, B Scheibe… - Chemical Society …, 2022 - pubs.rsc.org
Metal–organic gels (MOGs) emerged as a novel class of functional soft materials in which
the scaffolding framework is fabricated by metal–ligand coordination in combination with …

Permanently microporous metal–organic polyhedra

AJ Gosselin, CA Rowland, ED Bloch - Chemical reviews, 2020 - ACS Publications
As compared to porous network solids, including metal–organic frameworks, covalent–
organic frameworks, porous aromatic frameworks, and zeolites, porous molecular materials …

Rhodium-Based Metal–Organic Polyhedra Assemblies for Selective CO2 Photoreduction

AC Ghosh, A Legrand, R Rajapaksha… - Journal of the …, 2022 - ACS Publications
Heterogenization of molecular catalysts via their immobilization within extended structures
often results in a lowering of their catalytic properties due to a change in their coordination …

Hypercrosslinked polymer gels as a synthetic hybridization platform for designing versatile molecular separators

Y Su, Z Wang, A Legrand, T Aoyama… - Journal of the …, 2022 - ACS Publications
Hypercrosslinked polymers (HCPs), amorphous microporous three-dimensional networks
based on covalent linkage of organic building blocks, are a promising class of materials due …

Nanoarchitectonics for coordination asymmetry and related chemistry

K Ariga, M Shionoya - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
Nanoarchitectonics is a concept envisioned to produce functional materials from nanoscale
units through fusion of nanotechnology with other scientific disciplines. For component …

Post‐Assembly Modification of Homochiral Titanium–Organic Cages for Recognition and Separation of Molecular Isomers

GH Chen, YP He, Y Yu, H Lv, S Li… - Angewandte Chemie …, 2023 - Wiley Online Library
A chiral metal–organic cage (MOC) was extended and fixed into a porous framework using a
post‐assembly modification strategy, which made it easier to study the host–guest chemistry …

In Situ Gelled Covalent Organic Frameworks Electrolyte with Long-Range Interconnected Skeletons for Superior Ionic Conductivity

C Niu, S Zhao, Y Xu - Journal of the American Chemical Society, 2023 - ACS Publications
Covalent organic frameworks (COFs) present an ideal platform for ion transport owing to
their tunable and ordered nanochannels at the single-digit scale. However, achieving …

Metal–organic polyhedra as building blocks for porous extended networks

A Khobotov‐Bakishev, L Hernández‐López… - Advanced …, 2022 - Wiley Online Library
Metal–organic polyhedra (MOPs) are a subclass of coordination cages that can adsorb and
host species in solution and are permanently porous in solid‐state. These characteristics …