Herein, we report the synthesis of π-conjugation-extended vinyl sulfoxonium ylides from
vinyl sulfoxonium ylide and electron-deficient alkynes. The new dienoate ylides are used in …

One of the most important reactions of 1, 2, 3-triazines with a dienophile is inverse electron
demand Diels–Alder (IEDDA) cycloaddition, which occurs through nucleophilic addition to …

Vinyl diazo compounds are of great interest since they can both serve as carbene
precursors to react with nucleophiles and act as nucleophiles to react with electrophiles via …

The catalytic uses of metal carbenes for addition, insertion, and cycloaddition reactions are
dependent on their carbene precursor. The limited methods available for the preparation of …

Highly selective formal [3+ 2]-cycloaddition of vinyldiazoacetates with quinone ketals and
quinoneimine ketals has been accomplished at room temperature with catalytic amounts of …

A Lewis acid Sc (OTf) 3-catalyzed annulation reaction of vinyl diazoacetates with in situ
formed α, β-unsaturated imines for the preparation of indole-fused tricyclic rings has been …

1, 2, 3-Triazine 1-oxides are remarkably effective substrates for inverse electron demand
Diels–Alder reactions. Formed from vinyldiazoacetates via reaction with tert-butyl nitrite …

A novel DBU-promoted tandem cyclization reaction of ynones with diazo compounds as the
N-terminal electrophiles has been developed. The reaction provides a simple and efficient …

An unprecedented cycloaddition of vinyl diazo compounds with benzofuran-derived
azadienes catalyzed by rarely independently used NaBArF4 has been established …

Intramolecular addition reactions of electrophilic metallovinylcarbenes with nucleophiles that
do not have access to the carbene center undergo addition to the vinylogous position …