Conspectus Metalloproteins set the gold standard for performing important functions,
including catalyzing demanding reactions under mild conditions. Designing artificial …

Over the past decade, electrocatalytic reduction of CO 2 has gained substantial attention.
However, hardly any of the previous reviews have focused on the systematic discussion of …

The merger of photoredox and nickel catalysis has enabled the construction of quaternary
centers. However, the mechanism, role of the ligand, and effect of the spin state for this …

Well-defined molecular systems for catalytic hydrogen production that are robust, easily
generated, and active under mild aqueous conditions remain underdeveloped. Nickel …

Secondary sphere interactions are known to significantly impact catalytic rates within
biological systems as well as synthetic molecular catalysts. The [NiFe] hydrogenase …

Terminal NiIII hydrides are proposed intermediates in proton reduction catalyzed by both
molecular electrocatalysts and metalloenzymes, but well-defined examples of paramagnetic …

Efforts to drive catalytic reactions with light, inspired by natural processes like
photosynthesis, have a long history and have seen significant recent growth. Successfully …

The visible region of the electronic absorption spectra of Cu (II) complexes was studied by
time-dependent density functional theory (TD-DFT). The performance of twelve functionals in …

In order to enable the widespread use of renewable energy from sources such as solar and
wind, the energy needs to be stored for use when the renewable sources are not productive …

Hydrogenases are enzymes that catalyze the reversible conversion of hydrogen into protons
and electrons with high activity and efficiency. Recently, it was discovered that semisynthetic …