Polyethylene deconstruction to reusable smaller molecules is hindered by the chemical
inertness of its hydrocarbon chains. Pyrolysis and related approaches commonly require …

Rapid developments in materials engineering are accompanied by the equally rapid
development of new technologies, which are now increasingly used in various branches of …

The world's most abundantly manufactured plastic, polyethylene, consists of inert
hydrocarbon chains. The introduction of reactive polar groups in these chains could help …

As a typical layered transition metal chalcogenide, VS4 is considered as a promising
cathode material for advanced magnesium-ion batteries. However, the poor electronic …

In this paper, which is the first part of a more extended work, we elucidate the molecular
level structure of a highly active SiO 2-supported Ziegler-Natta precatalyst obtained by …

Being the main responsible for the huge production of polyolefins, heterogeneous Ziegler-
Natta catalysts are among the most important catalysts in the chemical industry and they …

Kinetics-based differences in the early stage fragmentation of two structurally analogous
silica-supported hafnocene-and zirconocene-based catalysts were observed during gas …

Performance enhancement of metallocene‐based olefin polymerization catalysts can be
obtained, among others, by the chemical modification of their support. We investigated a …

A full elucidation of chemisorbed donor behavior is of fundamental importance for tailoring
the active species but has not yet been achieved for Ziegler–Natta catalysts. Herein, by …

This short review summarizes the main results achieved in the field of operando
spectroscopies applied to heterogeneous catalysts for olefin polymerization. Following a …