A new heteroleptic polypyridyle Ru (II) complex was synthesized and deposited on surface
by the diazonium electroreduction process. It yields to the covalent grafting of a monolayer …

Nonlinear molecular interactions with optical fields produce intriguing optical phenomena
and applications ranging from color generation to biomedical imaging and sensing. The …

Sum frequency generation spectroscopy (SFG) and calculations of SFG spectra based on
density functional theory are combined to elucidate the orientation of two Re (R-2, 2 …

Controlling absorption and emission of organic molecules is crucial for efficient light-emitting
diodes, organic solar cells, and single-molecule spectroscopy. Here, a new molecular …

Abstract Demetalation of zinc 5, 10, 15, 20‐tetraphenylporphyrin (ZnTPP) under acidic
conditions and ion exchange with Cu2+ ions at neutral pH are both rapid reactions in the …

The coordination of PySSPy to FePc was monitored by UV/Vis spectroscopy while the
adsobed FePc, anchored by PyS− Au (111), was examined by in situ STM in 0.1 M HClO4 …

A new series of ruthenium organometallic carbon-rich complexes, exhibiting fast electron
transfer kinetics combined to a low oxidation potential, was synthesized for self-assembled …

Controlling the metalation of surface porphyrins is a critical process in porphyrin-based
devices. Indeed, surface porphyrins are known to metalate in ultrahigh vacuum from …

The insertion of a metal atom in the central cavity of adsorbed porphyrins is an important
subject as it allows specific control over the functionality of the molecule. In this work …

The molecular and electronic structure of Os (II) complexes covalently bonded to self-
assembled monolayers (SAMs) on Au (111) surfaces was studied by means of polarization …