Engineering inorganic interfaces using molecular nanolayers

G Ramanath, C Rowe, G Sharma… - Applied Physics …, 2023 - pubs.aip.org
Advances in interface science over the last 20 years have demonstrated the use of
molecular nanolayers (MNLs) at inorganic interfaces to access emergent phenomena and …

Low dielectric property of novel mesoporous silica/polymer composites using smart molecular caps: Theoretical calculation of air space encapsulated inside …

N Suzuki, S Kiba, Y Yamauchi - Microporous and Mesoporous Materials, 2011 - Elsevier
Here we demonstrate the fabrication of novel mesoporous silica/polymer composites using
smart molecular caps and investigate the low dielectric property. For the preparation of …

Mesoporous silica/polymer composites utilizing intelligent caps onto mesopore walls toward practical low-dielectric materials

S Kiba, Y Okawauchi, T Yanagihara… - Chemistry-An Asian …, 2009 - khu.elsevierpure.com
To put a cap on it: Intelligent caps have been added onto mesoporous walls toward
innovative low-dielectric materials. Appropriately sized caps at the mesopore entrance is …

Selective self-assembled monolayer coating to enable Cu-to-Cu connection in dual damascene vias

AM Caro, Y Travaly, G Beyer, Z Tokei, G Maes… - Microelectronic …, 2013 - Elsevier
In order to enable an oxide-free Cu-to-Cu bonding in a (dual) damascene process, 3-
aminopropyltrimethoxysilane-and decanethiol-derived self-assembled monolayers are …

Selective deposition of a cross-linked low-permittivity polycarbosilane on copper

B Singh, JY Hyun, AP Singh, D Gandhi… - … Applied Materials & …, 2010 - ACS Publications
Differential scanning calorimetry studies of the reaction of a cyclolinear polycarbosilane
[cyclo-(CH3Si (CH2) 2SiCH3)-(CH2) 6] n on air-exposed Cu surfaces reveal a substantial …

Highly Densified Mesoporous Bulk Silica Prepared with Colloidal Mesoporous Silica Nanoparticles toward a New Low-k Material

N Suzuki, YT Huang, Y Nemoto, A Nakahira… - Chemistry …, 2012 - academic.oup.com
We report the fabrication of highly densified mesoporous bulk silica consisting of colloidal
mesoporous silica nanoparticles (MSNs) by using a hydrothermal hot-pressing method. No …

Mechanical properties of low k SiO2 thin films templated by PVA

C Niu, X Wu, W Ren, X Chen, P Shi - Ceramics International, 2015 - Elsevier
Porous silica films as low-k interlayer dielectric were prepared via a sol–gel method.
Tetraethoxysilane (TEOS) was used as raw material and polyvinyl alcohol (PVA) with …

Tunable Mesoporous Phenolic-Silica Composites Templated by Poly (ethylene oxide-b-ε-caprolactone) Block Copolymer

WC Chu, L Dai, JK Chen, CF Huang… - Journal of Nanoscience …, 2016 - ingentaconnect.com
In this study, we prepared mesoporous composite materials templated by poly (ethylene
oxide-b-ε-caprolactone)(PEO-b-PCL) diblock copolymers with the matrix of TEOS and …

Effects of silylation on fracture and mechanical properties of mesoporous silica films interfaced with copper

DD Gandhi, B Singh, AP Singh, R Moore… - Journal of Applied …, 2009 - pubs.aip.org
Mesoporous silica (MPS) films are attractive for isolating Cu wiring in nanodevices but are
susceptible to pore wall collapse and water and metal uptake. Pore-sealing and chemical …

Effects of molecular functionalization sequence on mesoporous silica film properties

B Singh, S Garg, A Jain, R Moore… - Journal of Vacuum …, 2011 - pubs.aip.org
Functionalizing mesoporous silica (MPS) films with multiple organosilanes is attractive for
tailoring stable low permittivity (low k⁠) dielectrics for nanodevice wiring applications. Here …