One-electron and two-electron transfers in electrochemistry and homogeneous solution reactions

DH Evans - Chemical Reviews, 2008 - ACS Publications
Certainly one of the first topics to come to mind on seeing the term “molecular
electrochemistry” is the subject of electron-transfer reactions. In most cases, a multistep …

[HTML][HTML] Substituent effects in dinuclear paddlewheel compounds: electrochemical and spectroscopic investigations

T Ren - Coordination chemistry reviews, 1998 - Elsevier
This review summarizes substituent effects in dinuclear compounds supported by
diarylformamidinate (form) ligands, where aryl is phenyl substituted with various polar …

Diruthenium σ-alkynyl compounds: A new class of conjugated organometallics

T Ren - Organometallics, 2005 - ACS Publications
Reviewed herein are key aspects of the recent progress in the chemistry of σ-alkynyl
compounds of Ru2 (LL) 4, where LL is an N, N '-bidentate bridging ligand. Synthetic …

Polyyn-diyls capped by diruthenium termini: A new family of carbon-rich organometallic compounds and distance-dependent electronic coupling therein

GL Xu, G Zou, YH Ni, MC DeRosa… - Journal of the …, 2003 - ACS Publications
Polyyn-diyls capped by Ru2 (ap) 4 termini (ap= 2-anilinopyridinate), that is,[Ru2 (ap) 4](μ-C,
C '-C2 m)[Ru2 (ap) 4](compounds 1− 5 with m= 1− 4 and 6), were synthesized through either …

Strong electronic couplings between ferrocenyl centers mediated by bis-ethynyl/butadiynyl diruthenium bridges

GL Xu, RJ Crutchley, MC DeRosa, QJ Pan… - Journal of the …, 2005 - ACS Publications
A series of trans-(FcC2 n) Ru2 (Y-DMBA) 4 (C2 m Fc) with n, m= 1 and 2 and Y-DMBA as N,
N '-dimethylbenzamidinate or N, N '-dimethyl-(3-methoxy) benzamidinate have been …

Molecular and electronic structures by design: Tuning symmetrical and unsymmetrical linear trichromium chains

JF Berry, FA Cotton, T Lu, CA Murillo… - Journal of the …, 2004 - ACS Publications
The preparation, properties, and crystal structures of 12 trichromium extended metal atom
chain (EMAC) compounds of the type Cr3 (L) 4X2 (L= equatorial ligands dipyridylamide …

The use of amidinate ligands in paddlewheel diruthenium chemistry

M Cortijo, R Gonzalez-Prieto, S Herrero… - Coordination Chemistry …, 2019 - Elsevier
The amidinate anions have been widely used in the formation of dinuclear complexes with
paddlewheel structure. The higher donor character of this type of ligands, compared to …

Tetrakis(N,N'-dimethylbenzamidinato)diruthenium(III) Compounds Bearing Axial Chloro and Alkynyl Ligands:  A New Family of Redox Rich Diruthenium …

G Xu, C Campana, T Ren - Inorganic chemistry, 2002 - ACS Publications
Novel diruthenium (III) compound Ru2 (DMBA) 4Cl2 (1, DMBA= N, N '-
dimethylbenzamidinate) was obtained via refluxing Ru2 (OAc) 4Cl with …

An efficient synthesis of acetylide/trimetal/acetylide molecular wires

JF Berry, FA Cotton, CA Murillo, BK Roberts - Inorganic chemistry, 2004 - ACS Publications
Efficient syntheses are reported for incorporating trimetal units of the type M3 (dpa) 42+(M=
Cr, Co, Ni, and dpa= 2, 2 '-dipyridylamide) into polyalkynyl assemblies to give the …

[HTML][HTML] Ru-σ-alkynyl compounds of tetraanilinopyridinato-diruthenium (II, III) core: synthesis and structural characterization

G Zou, JC Alvarez, T Ren - Journal of Organometallic Chemistry, 2000 - Elsevier
Synthesis and characterizations are reported for three diruthenium (II, III) compounds of
general formula Ru2 (ap) 4 (C CR), where ap= 2-anilinopyridinate and R= Si (CH3) 3 (3) …