The crystal–liquid–glass phase transition of coordination polymers (CPs) and metal–organic
frameworks (MOFs) offers attractive opportunities as a new class of amorphous materials …

The melting phenomenon in metal–organic frameworks (MOFs) has been recognised as
one of the fourth generation MOF paradigm behaviours. Molten MOFs have high …

We describe the first meltable iron-based zeolitic imidazolate framework (ZIF), denoted MUV-
24. This material, elusive from direct synthesis, is obtained from the thermal treatment of [Fe3 …

Melt and glassy states of coordination polymers (CPs)/metal–organic frameworks (MOFs)
have gained attention as a new class of amorphous materials. Many bridging ligands such …

Glasses are typically formed by melt-quenching, that is, cooling of a liquid on a timescale
fast enough to avoid ordering to a crystalline state, and formerly thought to comprise three …

Superprotonic phase transition in CsHSO4 allows fast protonic conduction, but only at
temperatures above the transition temperature of 141° C (T c). Here, we preserve the …

Designing solid-state electrolytes for proton batteries at moderate temperatures is
challenging as most solid-state proton conductors suffer from poor moldability and thermal …

Recent studies on proton conductivity using pristine MOFs and their composite materials
have established an outstanding area of research owing to their potential applications for …

Through comprehensive analysis of carboxylate-based metal–organic frameworks (MOFs),
we present general evidence that challenges the common perception of MOF metal-linker …

Metal–organic framework (MOF) glasses provide new perspectives on many material
properties due to their unique chemical and structural nature. Their mechanical properties …