Palladium catalysis has achieved the status of an indispensable tool for both common and
state-of-theart organic synthesis. Among basic types of palladium-catalyzed transformations …

The rich legacy of arenediazonium salts in the synthesis of unsymmetrical biaryls, built
around the seminal works of Pschorr, Gomberg and Bachmann more than a century ago …

Abstract Triazenes (RN N NR′ R ″) are a class of compounds that hold much promise
in preparative chemistry as they are reactive groups which are both stable and adaptable to …

This review summarizes the recent advances made in the last ten years on Heck–Matsuda
couplings, involving aryl diazonium salts, in heterocyclic chemistry including natural …

In this review, we give a concise but complete overview of methods describing the use of
aryl diazonium salts in palladium-catalyzed reactions under safe conditions from a …

A range of diazonium salts and their corresponding triazenes have been prepared in order
to directly compare their relative thermal stabilities (via initial decomposition temperature) …

Triazene is one of the most versatile building blocks in organic synthesis. Generally, it is
viewed as a safe equivalent of diazonium salt, thus immediately finding numerous …

Aryltriazenes are directly coupled with areneboronic acids in the presence of a catalytic
amount of Pd2 (dba) 3 and P (t Bu) 3 together with 1 equiv of BF3⊙ OEt2 in DME to afford …

A new route to isoindazoles and cinnolines through the cyclization of (2-alkynylphenyl)
triazenes under neutral conditions is presented. The products that result from heating the …

1‐Aryltriazenes, the protected and more stable form of aryl‐diazonium species, can be
conveniently unmasked with Brønsted acidic‐IL or Sc (OTf) 3 and coupled with a host of …