The development of catalytic enantioselective transformations, enabling the construction of
complex molecular scaffolds from simple precursors, has been a long-standing challenge in …

The functionalization of C–H bonds has created new approaches to preparing organic
molecules by enabling new strategic “disconnections” during the planning of a synthetic …

This Perspective presents the fundamental principles, the elementary reactions, the initial
catalytic systems, and the contemporary catalysts that have converted C–H bond …

Transition metal complexes are efficient catalysts for the CH bond functionalization of
heteroarenes to generate useful products for the pharmaceutical and agricultural industries …

Methods that functionalize C–H bonds can lead to new approaches for the synthesis of
organic molecules, but to achieve this goal, researchers must develop site-selective …

The borylation of alkanes and arenes has become some of the most practical C–H bond
functionalization chemistry. Most striking is the high regioselectivity of these reactions …

A study on the iridium-catalyzed C–H borylation of heteroarenes is reported. Several
heteroarenes containing multiple heteroatoms were found to be amenable to C–H borylation …

Regioselective C–H functionalization of arenes has widespread applications in synthetic
chemistry. The regioselectivity of these reactions is often controlled by directing groups or …

Complete control of the product of a catalytic reaction can be achieved on the basis of
catalyst structure, even when the reaction conditions are nearly identical. Catalyst‐controlled …

The iridium‐catalysed borylation of aromatic C− H bonds has become the preferred method
for the synthesis of aromatic organoboron compounds. The reaction is highly efficient …