Photoinduced Co/Ni-cocatalyzed Markovnikov hydroarylation of unactivated olefins with aryl bromides

HC Liu, XY Xu, S Tang, J Bao, YZ Wang, Y Chen… - Chemical …, 2024 - pubs.rsc.org
Transition-metal-catalyzed hydroarylation of unactivated alkenes via metal hydride
hydrogen atom transfer (MHAT) is an attractive approach for the construction of C (sp2)–C …

Nickel-Catalyzed Enantio-and Diastereoselective Synthesis of Fluorine-Containing Vicinal Stereogenic Centers

U Dhawa, L Lavrencic, X Hu - ACS Central Science, 2024 - ACS Publications
The construction of fluorinated architectures has been a topic of interest to medicinal
chemists due to their unique ability to improve the pharmacokinetic properties of bioactive …

Defluorinative haloalkylation of unactivated alkenes enabled by dual photoredox and copper catalysis

S Li, X Li, K Zhao, X Yang, J Xu… - The Journal of Organic …, 2024 - ACS Publications
A three-component defluorinative haloalkylation of alkenes with trifluoromethyl compounds
and TBAX (X= Cl, Br) via dual photoredox/copper catalysis is reported. The mild conditions …

Regio-and enantioselective hydrofluorination of internal alkenes via nickel-catalyzed hydrogen atom transfer

F Chen, X Zhao, W Miao, Y Li, Y Yuan, L Chu - Chinese Chemical Letters, 2024 - Elsevier
Here we present a highly efficient protocol utilizing nickel-hydride hydrogen atom transfer
catalysis for the regio-and enantioselective hydrofluorination of internal alkenes. This …

Electrooxidative Pd-Catalyzed Remote Hydrofunctionalization of Alkenes with Nucleophiles

S Park, B Yang, D Lee, H Kim, K Shin - ACS Catalysis, 2024 - ACS Publications
The catalytic hydrofunctionalization of alkenes with nucleophiles via the generation of
carbocationic intermediates has been extensively studied as an efficient strategy for the …

Nonheme Mononuclear and Dinuclear Iron (II) and Iron (III) Fluoride Complexes and Their Fluorine Radical Transfer Reactivity

V Yadav, L Wen, S Yadav, MA Siegler… - Inorganic …, 2025 - ACS Publications
The nonheme iron (II) complexes containing a fluoride anion, FeII (BNPAPh2O)(F)(1) and
[FeII (BNPAPh2OH)(F)(THF)](BF4)(2), were synthesized and structurally characterized …

Nickel-Catalyzed Regio-and Enantioselective Hydrofluorination in Unactivated Alkenes

M Kim, S Han, S Hong - Synlett, 2025 - thieme-connect.com
While enantioselective hydrofluorination methods for activated alkenes represent a notable
advance, the resultant enantiomeric excesses remain largely moderate, indicating the …

Directed Regio-and Enantioselective Hydrofluorination of Alkenes Under Nickel Hydride Catalysis

M Oestreich, HFT Klare, EA Bolomey - Synfacts, 2024 - thieme-connect.com
Directed Regio- and Enantioselective Hydrofluorination of Alkenes Under Nickel Hydride
Catalysis Page 1 614 © 2024. Thieme. All rights reserved. Georg Thieme Verlag KG …