Iron photoredox catalysis–past, present, and future

LHM de Groot, A Ilic, J Schwarz… - Journal of the American …, 2023 - ACS Publications
Photoredox catalysis of organic reactions driven by iron has attracted substantial attention
throughout recent years, due to potential environmental and economic benefits. In this …

The great strides of iron photosensitizers for contemporary organic photoredox catalysis: On our way to the holy grail?

F Glaser, A Aydogan, B Elias… - Coordination Chemistry …, 2024 - Elsevier
The scarcity of 2 nd and 3 rd row transition metals such as ruthenium, iridium, rhodium and
osmium, coupled with a global desire for sustainable chemistry has led to the resurgence of …

Highly enantioselective radical cation [2+ 2] and [4+ 2] cycloadditions by chiral iron (III) photoredox catalysis

S Ohmura, K Katagiri, H Kato, T Horibe… - Journal of the …, 2023 - ACS Publications
Radical cations show a unique reactivity that is fundamentally different from that of
conventional cations and have thus attracted considerable attention as alternative cationic …

Aminomethylations of electron-deficient compounds—bringing iron photoredox catalysis into play

A Ilic, BR Strücker, CE Johnson, S Hainz, R Lomoth… - Chemical …, 2024 - pubs.rsc.org
The α-functionalisation of N-containing compounds is an area of broad interest in synthetic
chemistry due to their presence in biologically active substances among others. Visible light …

Comprehensive characterization of octahedral Co3O4 doped with Cu induces oxygen vacancies as a battery-type redox active electrode material for supercapacitors

S Kumar, L Reddy, MR Hatshan, N Roy, JS Kim… - Ceramics …, 2024 - Elsevier
The urgent need to combat global warming has spurred the exploration of renewable energy
solutions, among which the supercapacitor has emerged as a promising contender for …

Counterion Effects in [Ru(bpy)3](X)2-Photocatalyzed Energy Transfer Reactions

J Zanzi, Z Pastorel, C Duhayon, E Lognon, C Coudret… - JACS Au, 2024 - ACS Publications
Photocatalysis that uses the energy of light to promote chemical transformations by
exploiting the reactivity of excited-state molecules is at the heart of a virtuous dynamic within …

Visible-Light-Induced Cascade Cyclization of 1-Acryloyl-2-cyanoindole: Access of Difluoroalkylated Pyrrolo[1,2-a]indolediones

J Yuan, L Shen, N Guo, Y Yin, P Yang… - The Journal of …, 2023 - ACS Publications
An effective method for accessing diverse difluoroalkylated pyrrolo [1, 2-a] indolediones via
visible-light-induced PhI (OAc) 2-promoted cascade difluoroalkylation/cyclization reaction …

Recent advances in radical-mediated intermolecular (4+ 2) cycloaddition

XE Cai, ZY Wang, WC Tian, H Liu, WT Wei… - Organic & Biomolecular …, 2023 - pubs.rsc.org
(4+ 2) Cycloaddition plays an important role in the synthesis of versatile carbocyclic/
heterocyclic compounds with its high atom-and step-economy. Additionally, with mild …

Mechano-photoexcitation for organic synthesis using mechanoluminescent materials as photon sources

X Xin, J Geng, D Zhang, HT Ang, H Wang, Y Cheng… - Nature …, 2024 - nature.com
Implementing photochemical reactions through mechanochemical methods can reduce
waste generation by eliminating the need for bulk solvents. The absence of solvent results in …

Visible-Light-Induced Iron Group Metal Catalysis: Recent Developments in Organic Synthesis

C Yin, M Wang, Z Cai, B Yuan, P Hu - Synthesis, 2022 - thieme-connect.com
One central research goal for modern organic chemistry in society is to develop sustainable
synthetic methodologies. Visible-light-induced transformations that apply earth-abundant …