Dearomatization reactions provide rapid access to structurally complex three-dimensional
molecules from simple aromatic compounds. Plenty of reports have demonstrated their …

Conspectus Exploring the enormous chemical space through an expedient building-up of
molecular diversity is an important goal of organic chemistry. The development of synthetic …

Hybrid fused two-dimensional/three-dimensional (2D/3D) rings are important
pharmacophores in drugs owing to their unique structural and physicochemical properties …

Photochemical dearomative cycloaddition has emerged as a useful strategy to rapidly
generate molecular complexity. Within this context, stereo-and regiocontrolled …

Visible-light-induced cycloaddition reactions initiated via energy-transfer processes have
recently evolved as powerful methods for the construction of strained cyclic molecules that …

The rapid buildup of molecular complexity from simple precursors is a key goal in organic
chemistry. One strategy to achieve this is through a dearomative cycloaddition wherein a 2D …

Herein we report visible‐light‐induced intramolecular double dearomative cycloaddition of
arenes. Compared with the well‐known photodimerization of arenes under ultraviolet …

Abstract (Hetero) arene reduction is one of the key avenues for synthesizing related cyclic
alkenes and alkanes. While catalytic hydrogenation and Birch reduction are the two broadly …

Abstract A direct dearomative photocatalyzed (3+ 2) cycloaddition between indoles and
vinyldiazo reagents is described. The transformation is enabled by the development of a …

The facile construction of C (sp3)‐rich carbo‐and heterocyclic compounds is a pivotal
synthetic strategy to foster contemporary drug discovery programs. The downstream …