Oxidative halogenation with “green” oxidants: oxygen and hydrogen peroxide

A Podgoršek, M Zupan, J Iskra - … Chemie International Edition, 2009 - Wiley Online Library
It is difficult to imagine organic chemistry without organo‐halogen compounds and the
molecular halogens needed for their preparation. The halogens have very different …

Bromide oxidation: A safe strategy for electrophilic brominations

R Van Kerrebroeck, T Horsten… - European Journal of …, 2022 - Wiley Online Library
Bromination of organic substances is still an important reaction in modern synthetic
chemistry. In view of the increasing demand for sustainable synthetic chemistry, oxidative …

Selective catalytic oxidation of ethylbenzene to acetophenone: a review of catalyst systems and reaction mechanisms

MO Azeez, SA Nafiu, TA Olarewaju… - Industrial & …, 2023 - ACS Publications
Acetophenone is an important chemical intermediate often employed in the production chain
of many pharmaceuticals, agrochemicals, food, and cosmetic products. It is industrially …

Direct and selective benzylic oxidation of alkylarenes via C–H abstraction using alkali metal bromides

K Moriyama, M Takemura, H Togo - Organic letters, 2012 - ACS Publications
A direct benzylic oxidation of alkylarenes via C–H bond abstraction was developed using
alkali metal bromides and oxidants under mild conditions. This reaction proceeded with …

Visible light mediated efficient oxidative benzylic sp 3 C–H to ketone derivatives obtained under mild conditions using O 2

H Yi, C Bian, X Hu, L Niu, A Lei - Chemical Communications, 2015 - pubs.rsc.org
A photooxygenation of benzylic sp3 C–H reaction has been demonstrated using O2
mediated by visible light. This protocol provides a simple and mild route to obtain ketones …

Hydrogen Peroxide-Mediated Rapid Room Temperature Metal-Free C(sp2)-H Thiocyanation of Amino Pyrazoles, Amino Uracils, and Enamines

D Ali, AK Panday, LH Choudhury - The Journal of Organic …, 2020 - ACS Publications
A rapid metal-and additive-free room temperature method for C (sp2)-H thiocyanation of
aminopyrazoles, aminoisoxazole, aminoisothiazole, amino uracils, and aliphatic enamines …

Clean and efficient benzylic C− H oxidation in water using a hypervalent iodine reagent: activation of polymeric iodosobenzene with KBr in the presence of …

T Dohi, N Takenaga, A Goto, H Fujioka… - The Journal of Organic …, 2008 - ACS Publications
We have found that unreactive and insoluble polymeric iodosobenzene [PhIO] n induced
aqueous benzylic C− H oxidation to effectively give arylketones, in the presence of KBr and …

Selective electrochemical oxidation of aromatic hydrocarbons and preparation of mono/multi-carbonyl compounds

Z Li, Y Zhang, K Li, Z Zhou, Z Zha, Z Wang - Science China Chemistry, 2021 - Springer
A selective electrochemical oxidation was developed under mild condition. Various mono-
carbonyl and multi-carbonyl compounds can be prepared from different aromatic …

A metal-free catalytic system for the oxidation of benzylic methylenes and primary amines under solvent-free conditions

J Zhang, Z Wang, Y Wang, C Wan, X Zheng… - Green Chemistry, 2009 - pubs.rsc.org
Iodine–pyridine–tert-butylhydroperoxide is developed as a green and efficient catalytic
system for the oxidation of benzylic methylenes to ketones and primary amines to nitriles …

Homogeneous liquid-phase oxidation of ethylbenzene to acetophenone in continuous flow mode

B Gutmann, P Elsner, D Roberge, CO Kappe - Acs Catalysis, 2013 - ACS Publications
The oxidation of ethylbenzene with hydrogen peroxide and molecular oxygen catalyzed by
cobalt and bromide ions in acetic acid as solvent was studied. The oxidation of …