Currently, the chemistry of organofluorine compounds is a leading and rapidly developing
area of organic chemistry. Fluorine present in a molecule largely determines its specific …

The challenges of the modern society and the growing demand of high-technology sectors
of industrial production bring about a new phase in the development of organic synthesis. A …

The involvement of manganese radical for halogen atom transfer (XAT) reactions has been
esteemed as one reliable method but encountered with limited catalytic models. In this …

Transition-metal-mediated fluoroalkylation is a hot research topic in current organofluorine
chemistry. In the past five years, due to the development of new perfluoroalkylation reagents …

Controllable fluorocarbon chain elongation (CFCE) is a promising yet underdeveloped
strategy for the well-defined synthesis of structurally novel polyfluorinated compounds …

An electroreductive cross-coupling of prop-2-yn-1-yl acetates with chloro (vinyl) silanes for
producing tetrasubstituted silylallenes is developed. The method enables the formation of a …

A method for nucleophilic difluoromethylation of reactive Michael acceptors, aldehydes, and
azomethines is described. The reaction is performed using the readily available and air …

One way to introduce fluorine into a molecule is through fluoroalkylation reactions.
Transition-metal catalysts play an increasing role in selectively incorporating fluoroalkyl …

The palladium-catalyzed Negishi cross-coupling reaction of aryl iodides and bromides with
(difluoromethyl) zinc reagent bearing a diamine such as TMEDA is achieved to provide the …

There have been significant developments in the area of perfluoroalkyl group transfer using
silicon reagents, specifically in nucleophilic trifluoromethylation. The mild and versatile …