Mechanistic aspects of C− H activation by Pt complexes

M Lersch, M Tilset - Chemical reviews, 2005 - ACS Publications
Hydrocarbons are readily available from inexpensive petrochemical and natural gas
feedstock and have been utilized as raw materials for the production of materials and energy …

Cooperative catalysis with first‐row late transition metals

JI van der Vlugt - European Journal of Inorganic Chemistry, 2012 - Wiley Online Library
Cooperative catalysis with first‐row transition metals holds much promise for future
developments regarding sustainable, selective transformations, including eg alkenes …

Regioselective Introduction of Heteroatoms at the C-8 Position of Quinoline N-Oxides: Remote C–H Activation Using N-Oxide as a Stepping Stone

H Hwang, J Kim, J Jeong, S Chang - Journal of the American …, 2014 - ACS Publications
Reported herein is the metal-catalyzed regioselective C–H functionalization of quinoline N-
oxides at the 8-position: direct iodination and amidation were developed using rhodium and …

Metal complexes of chelating diarylamido phosphine ligands

LC Liang - Coordination chemistry reviews, 2006 - Elsevier
This review summarizes the recent progress in coordination and organometallic chemistry
involving metal complexes of chelating diarylamido phosphine ligands, including bidentate …

Homogeneous hydrocarbon CH bond activation and functionalization with platinum

U Fekl, KI Goldberg - Adv. Inorg. Chem, 2003 - books.google.com
A. On the Direct Oxidative Addition of RH to Square-planar Pt (II) B. Activation of RH by Pt (II)
Complexes Possessing a Labile Ligand C. Five-coordinate Pt (IV) Intermediates and Pt (II) σ …

Mechanisms of C− C and C− H Alkane Reductive Eliminations from Octahedral Pt (IV): Reaction via Five-Coordinate Intermediates or Direct Elimination?

DM Crumpton-Bregel, KI Goldberg - Journal of the American …, 2003 - ACS Publications
The Pt (IV) complexes P2PtMe3R [P2= dppe (PPh2 (CH2) 2PPh2), dppbz (o-PPh2 (C6H4)
PPh2); R= Me, H] undergo reductive elimination reactions to form carbon− carbon or …

Oxidative addition of N− C and N− H bonds to zerovalent nickel, palladium, and platinum

OV Ozerov, C Guo, L Fan, BM Foxman - Organometallics, 2004 - ACS Publications
Reactions of chelating pincer-type PNP ligands based on the bis (ortho-phosphinoaryl)
amine substructure and containing either an N− H (PN (H) P, 1) or N− Me (PN (Me) P, 2) …

Luminescent Platinum(II) Complexes of N^N^N Amido Ligands with Benzannulated N-Heterocyclic Donor Arms: Quinolines Offer Unexpectedly Deeper Red …

P Mandapati, JD Braun, C Killeen, RL Davis… - Inorganic …, 2019 - ACS Publications
A platform for investigating the impact of π-extension in benzannulated, anionic pincer-type
N^ N–^ N-coordinating amido ligands and their Pt (II) complexes is presented. Based on bis …

Ag NMR as a tool for mechanistic studies of Ag-catalyzed reactions: Evidence for in situ formation of alkyn-1-yl silver from alkynes and silver salts

U Létinois-Halbes, P Pale, S Berger - The Journal of organic …, 2005 - ACS Publications
As demonstrated by 1H, 13C, and 109Ag NMR, a π-alkyne-Ag complex and then an alkynyl
silver are in situ formed from alkyne and silver salt in conditions related to those used for Ag …

Nickel Complexes of a Pincer Amidobis (amine) Ligand: Synthesis, Structure, and Activity in Stoichiometric and Catalytic C C Bond‐Forming Reactions of Alkyl …

O Vechorkin, Z Csok, R Scopelliti… - Chemistry–A European …, 2009 - Wiley Online Library
Get a grip! NiII complexes of the new pincer amidobis (amine) ligand are described. The Ni
chloride complex catalyzes Kumada–Corriu–Tamao coupling of unactivated alkyl halides …