For the first-row middle transition metals (Cr, Mn, and Fe), the formal oxidation states are
relatively lower. However, biological systems in various enzymatic reactions rely extensively …

de Visser et al. demonstrated theoretically that although vanadium (IV)-oxo complexes are
slow oxidants, in the presence of H2O2 they generated a side-on vanadium-peroxo …

Precisely modulating the coordination environment of active centers in single-atom catalysts
(SACs) remains a significant challenge. Herein, a Ru-Pd dual single atoms (SAs)(exist as …

A new method of activating corrole macrocycles via an in situ generated SCN radical has
been developed at very mild conditions at room temperature. This photoredox reaction …

Sharpless et al. have described, while performing the molybdenum-catalyzed epoxidation
reaction of olefins using alkyl hydroperoxides, that the molybdenum-oxo moiety is an active …

Metal‐versus ligand‐centered redox processes and the effects of substituents on the ligands
on the spectroscopic properties of the metal complexes are at the heart of research on metal …

A remarkable rearrangement of a diferrocenylporphyrin to give a silver (III) corrole has been
discovered. Compared to the previously reported porphyrin to corrole ring conversions …

Metal complexes bearing nitrido ligands (M≡ N) are at the forefront of current scientific
research due to their resemblances with the metal complexes involved in the nitrogen …

Two corrolato-antimony (III) complexes have been prepared for the first time and
characterized by a series of spectroscopic techniques. Both the complexes have been …

Herein we demonstrate a synthetic protocol for the regioselective thiocyanation of corroles.
To the best of our knowledge, thiocyanato appended corrole has never been reported …