Hydrogen spillover. Facts and fiction

R Prins - Chemical reviews, 2012 - ACS Publications
1. INTRODUCTION In 1964, Khoobiar reported that WO3 is reduced by H2 to blue WO3− x
when it is in contact with a Pt catalyst. 1 The blue color appears because hydrogen atoms …

Surface intermediates steer the pathways of CO2 hydrogenation on Pt/γ-Al2O3: Importance of the metal-support interface

Q Wu, H Li, G Yang, Y Cao, H Wang, F Peng, H Yu - Journal of Catalysis, 2023 - Elsevier
A variety of adsorbed intermediates have been extensively assigned during CO 2
hydrogenation on Pt/γ-Al 2 O 3. However, the surface sites where the surface species reside …

Tuning the Rh–FeOx Interface in Ethanol Synthesis through Formation Phase Studies at High Pressures of Synthesis Gas

P Preikschas, M Plodinec, J Bauer, R Kraehnert… - ACS …, 2021 - ACS Publications
As-prepared materials tested for a catalytic reaction are usually only precatalysts that
become active and/or selective under specific conditions. During this initial formation phase …

Synergistic interaction between oxides of copper and iron for production of fatty alcohols from fatty acids

K Kandel, U Chaudhary, NC Nelson, II Slowing - ACS Catalysis, 2015 - ACS Publications
The selective hydrogenation of fatty acids to fatty alcohols can be achieved under moderate
conditions (180° C, 30 bar H2) by simultaneously supporting copper and iron oxides on …

Pt, Ir, Ru, and Rh nanoparticles supported on ZIF-67 nanocubes for evaluation of hydrogen spillover ability of noble metals

Y Shao, HC Zeng - ACS Applied Nano Materials, 2021 - ACS Publications
The hydrogen spillover phenomenon offers a great potential for enhanced performance in
heterogeneous catalysis involving hydrogenation. Despite this, the current applications of …

Role of Pt in Pt/SO42−-ZrO2 catalyzed n-butane isomerization reaction: Hydrogen spillover rather than bifunctional “metal-acid” catalysis

P Wang, T Zeng, W Yao, Y Wang, D Zhao, M Zhang… - Molecular …, 2023 - Elsevier
The understanding of reaction mechanism is the key to develop the highly efficient catalyst.
The introduction of Pt on SO 4 2−/ZrO 2 surface greatly improves its catalytic stability in n …

Preparation and characterization of Fe, Co, Si-pillared montmorillonites with aminosilanes as silicon pillars precursor

L Fang, L Wang, T Zhou, L Liu, J Zhou, M Li - Applied Clay Science, 2017 - Elsevier
Abstract Fe, Co, Si-pillared montmorillonites with micro-and mesopores and high thermal
stability were prepared by directly introducing transition metal ions (Fe and Co) and …

New bifunctional catalyst based on Pt containing layered silicate Na-ilerite

A Kuhlmann, F Roessner, W Schwieger, O Gravenhorst… - Catalysis today, 2004 - Elsevier
Silica-supported Pt nanoparticles were prepared by intercalation of [Pt (NH3) 4] 2+ ions into
layered silicate Na-ilerite. This material, with a high amount of Pt (20 wt.%), was used as a …

Naphthalene hydrogenation using Rh/Fe2O3-TiO2 magnetic catalysts

I Cuauhtémoc-López, A Jiménez-Vázquez… - Catalysis Today, 2021 - Elsevier
Two magnetic catalysts were synthesized by a modification route and applied into the
naphthalene hydrogenation at 553 K. For this propose, Fe 2 O 3-TiO 2 support and Rh/Fe 2 …

Enhanced reduction of Fe2O3 caused by migration of TM ions out of zeolite channels

OE Lebedeva, WMH Sachtler - Journal of Catalysis, 2000 - Elsevier
Theoretical models do not predict significant hydrogen spillover from metal particles to the
surface of a nonconducting oxide in the absence of a high concentration of OH groups. This …