Metal–organic self-assembly with flexible moieties is a budding field of research due to the
possibility of the formation of unique architectures. Tetrazole, characterised by four nitrogen …

The effect of host–guest interactions on the chemistry of encapsulated molecules is a
fascinating field of research that has gained momentum in recent years. Much of the work in …

Although the fundamental configuration (tetrahedron-type and capsule-type) of Zr-MOCs is
well understood, the synthesis of amino-functionalized Zr-based capsule (denoted as ZrC-1 …

Metal–organic cages (MOCs) are discrete supramolecular entities consisting of metal nodes
and organic connectors or linkers; MOCs are noted for their high porosity and processability …

In this study, we scrutinized the self-assembly dynamics of mixed-ligand MOCs employing
HR-MS. Our findings unveiled the remarkable coexistence of tetrahedron and cigar …

Zirconium-based porous coordination cages have been widely studied and have shown to
be potentially useful for many applications as a result of their tunability and stability, likely as …

Fast ultrasound-assisted processes were utilized for the first time, to achieve the successful
synthesis of two highly crystalline Zr-based metal-organic cages, namely ZrT-1 and ZrT-1 …

Zirconium-based metal-organic cages (Zr-MOCs) typically exhibit high stability, but their
structural and application reports are scarce due to stringent crystallization conditions. We …

Herein, a novel CF 3-functionalized zirconium-based metal-organic tetrahedron (ZrT-(CF 3)
2) was constructed based on 2.5-bis (trifluoromethyl) terephthalic acid (H 2 BDC-(CF 3) 2) …

Several synthetic approaches, such as solvothermal, microwave-assisted, electrochemical,
and mechanochemical techniques, are used in the creation of metal-organic frameworks …