Emerging Trends in Cross-Coupling: Twelve-Electron-Based L1Pd(0) Catalysts, Their Mechanism of Action, and Selected Applications

SJ Firsan, V Sivakumar, TJ Colacot - Chemical Reviews, 2022 - ACS Publications
Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

Mechanistic aspects of the palladium‐catalyzed Suzuki‐Miyaura cross‐coupling reaction

MC D'Alterio, È Casals‐Cruañas… - … A European Journal, 2021 - Wiley Online Library
The story of C− C bond formation includes several reactions, and surely Suzuki‐Miyaura is
among the most outstanding ones. Herein, a brief historical overview of insights regarding …

A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms

C Sandford, MA Edwards, KJ Klunder, DP Hickey… - Chemical …, 2019 - pubs.rsc.org
Monitoring reactive intermediates can provide vital information in the study of synthetic
reaction mechanisms, enabling the design of new catalysts and methods. Many synthetic …

The Suzuki-Miyaura reaction after the Nobel prize

IP Beletskaya, F Alonso, V Tyurin - Coordination Chemistry Reviews, 2019 - Elsevier
Synthetic organic chemistry experienced a significant advance in the last quarter of the 20th
century with the advent of the transition-metal catalyzed cross-coupling reactions. The utility …

Conducting polymers for optoelectronic devices and organic solar cells: A review

A R. Murad, A Iraqi, SB Aziz, S N. Abdullah, MA Brza - Polymers, 2020 - mdpi.com
In this review paper, we present a comprehensive summary of the different organic solar cell
(OSC) families. Pure and doped conjugated polymers are described. The band structure …

Solvent effects in palladium catalysed cross-coupling reactions

J Sherwood, JH Clark, IJS Fairlamb, JM Slattery - Green Chemistry, 2019 - pubs.rsc.org
Palladium catalysed cross-couplings reactions have been a dominant method in synthetic
chemistry for decades. Despite this, the role of the solvent is often taken for granted and …

Selection of boron reagents for Suzuki–Miyaura coupling

AJJ Lennox, GC Lloyd-Jones - Chemical Society Reviews, 2014 - pubs.rsc.org
Suzuki–Miyaura (SM) cross-coupling is arguably the most widely-applied transition metal
catalysed carbon–carbon bond forming reaction to date. Its success originates from a …

Computational studies of synthetically relevant homogeneous organometallic catalysis involving Ni, Pd, Ir, and Rh: an overview of commonly employed DFT methods …

T Sperger, IA Sanhueza, I Kalvet… - Chemical …, 2015 - ACS Publications
The field of organometallic catalysis has attracted considerable interest from both academia
and industry due to its broad applications in synthetic transformations. Pd, Ni, Rh, and Ir …

Mechanistic Investigations of Phenoxyimine–Cobalt(II)-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross-Coupling

LR Mills, D Gygi, EM Simmons… - Journal of the …, 2023 - ACS Publications
The mechanism of phenoxyimine (FI)− cobalt-catalyzed C (sp2)–C (sp3) Suzuki–Miyaura
cross-coupling was studied using a combination of kinetic measurements and catalytic and …

Palladium‐catalyzed cross‐coupling: a historical contextual perspective to the 2010 Nobel Prize

CCC Johansson Seechurn, MO Kitching… - Angewandte Chemie …, 2012 - Wiley Online Library
Abstract In 2010, Richard Heck, Ei‐ichi Negishi, and Akira Suzuki joined the prestigious
circle of Nobel Laureate chemists for their roles in discovering and developing highly …