The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …

Flow, heat, and mass transfer in fixed beds of catalyst particles are complex phenomena
and, when combined with catalytic reactions, are multiscale in both time and space; …

Abstract Single‐atomic‐site (SAS) catalysts, a new frontier of catalysts, always show
extremely high atom efficiency and unexpected catalytic properties. Herein, a pyrolyzing …

Propylene epoxidation with O2 to propylene oxide is a very valuable reaction but remains as
a long-standing challenge due to unavailable efficient catalysts with high selectivity. Herein …

Taking 50 years of effort, ambient pressure X-ray photoelectron spectroscopy (APXPS) has
become a useful characterization tool for studies in heterogeneous catalysis and …

We employed machine learning-augmented density functional theory (DFT) thermodynamic
calculations to assess the stability of different AgO x structures under catalytic ethylene …

Today ethylene oxide can be produced industrially with~ 90% selectivity through the
epoxidation of ethylene over silver catalyst. The past decades there has been a substantial …

Chemistry on solid surfaces is central to many areas of practical interest such as
heterogeneous catalysis, tribology, electrochemistry, and materials processing. With the …

Selective epoxidation of various alkenes with molecular oxygen (O2) under mild conditions
is a longstanding challenge in achieving syntheses of epoxides. Cu-based catalysts have …

Tris (pyrazolyl) borates, first reported about 40 years ago, are a very useful class of
monoanionic, nitrogen-based, auxiliary ligands in coordination and organometallic and …