C–H borylation is one of the powerful C–H bond functionalization reactions. In this context, a
metal-free C–H borylation of benzophenones using hydrazone as the traceless directing …

Two methoxy-substituted tetraphenylethylene (TPE) derivatives, tetra (4-methoxyphenyl)
ethylene (TMOE) and tetra (3, 4-dimethoxyphenyl) ethylene (TDMOE), were synthesized by …

Tetraarylethylenes can be sequentially transformed into 9, 10-diarylphenanthrenes and
dibenzo [g, p] chrysenes using 1 and 2 equiv of DDQ, respectively, in CH2Cl2 containing …

The extended polycyclic aromatic hydrocarbons (PAHs) have received significant
interdisciplinary attention due to their semiconducting applications in diverse organic …

Magic blue (MB+˙ SbCl6− salt), ie tris-4-bromophenylamminium cation radical, is a routinely
employed one-electron oxidant that slowly decomposes in the solid state upon storage to …

We investigated the chemical and physical properties of internally functionalized dibenzo [g,
p] chrysene (DBC) derivatives. These molecules exhibit chiral double-helicene-like …

The spontaneous assembly of aromatic cation radicals (D+•) with their neutral counterpart
(D) affords dimer cation radicals (D 2+•). The intermolecular dimeric cation radicals are …

By using N, N-dimethylformamide (DMF) as a CO source, the cheap metal nickel-catalyzed
carbonylation of arylboronic acids was demonstrated as an efficient and facile protocol for …

Redox properties of polycyclic aromatic hydrocarbons (PAHs) can be modulated by
substitution with electron-rich groups. Here we show, using the example of dibenzo [g, p] …

Here, we report two series (denoted as meta and para) of π-extended dibenzo [g, p]
chrysenes (DBCs) with different substituents (H, Me and OMe). These six novel compounds …