Recent advances in the synthesis of sulfur (VI)-fluorides has enabled incredible growth in
their application in biomolecular chemistry. This review aims to serve as a primer …

The development of rapid, selective, and sensitive fluorescent sensors is essential for
visualizing and quantifying biological molecules and processes in vitro, ex vitro, and in vivo …

Sulfonyl fluoride (SF) containing substances are currently attracting enormous attention
among practitioners of both chemical biology and synthetic organic chemistry. The groups of …

A palladium‐catalyzed fluorosulfonylvinylation reaction of organic iodides is described.
Catalytic Pd (OAc) 2 with a stoichiometric amount of silver (I) trifluoroacetate enables the …

Herein, we report a new method for the one-pot syntheses of sulfonyl fluorides. Addition of
an alkyl, aryl, or heteroaryl Grignard to a solution of sulfuryl fluoride at ambient temperature …

The syntheses and applications of fluorosulfonylated organic compounds have flourished in
the last ten years due to their versatility to participate in click chemistry (SuFEx) reactions …

The reactive functionalities of drugs that engage in covalent interactions with the
enzyme/receptor residue in either a reversible or an irreversible manner are …

Herein, we report an operationally simple, ligand-and additive-free oxidative boron-Heck
coupling that is compatible with the ethenesulfonyl fluoride functional group. The protocol …

The sulfur (VI) fluoride exchange reaction (SuFEx), developed by Sharpless and co-workers
in 2014, is a new category of click reaction that creates molecular connections with absolute …

A new fluorosulfonylation reagent 1-bromoethene-1-sulfonyl fluoride was developed (1-Br-
ESF). This unique reagent possesses three addressable handles (vinyl, bromide, and …