Oxide dielectric materials play a key role in a wide range of high-performance solid-state
electronics from semiconductor devices to emerging wearable and soft bioelectronic …

Abstract Nanocrystalline basaluminite [Al 4 OH 10 (SO 4)·(H 2 O) 3–5] and aggregation of
the ε-Keggin polyoxocation [Al 12 (AlO 4)(OH) 24 (H 2 O) 12] 7+, referred to as Al 13, have …

Recent interest in the crystal structure of natrophosphate (Na7FPO4· 19H2O) has sought to
better understand the propensity of this phase to vary in composition through either …

Examining isotopically 15N-labeled versions of 1, 3, 5-triamino-2, 4, 6-trinitrobenzene
(TATB) by NMR has experimentally demonstrated the effects of strong intra-and …

Although nanometer‐sized aluminum hydroxide clusters (ie, ϵ‐Al13,[Al13O4 (OH) 24 (H2O)
12] 7+) command a central role in aluminum ion speciation and transformations between …

The role of oligomeric aluminate species in the precipitation of aluminum (Al) phases such
as gibbsite (α-Al (OH) 3) from aqueous hydroxide solutions remains unclear and difficult to …

Trivalent bismuth is a unique heavy p-block ion. It is highly insoluble in water, due to strong
hydrolysis tendencies, and known for low toxicity. Its lone pair is structure-directing …

Given the ubiquity of glass formulations that are functionalized with silver compounds, the
electronic interaction between isolated silver cations and the glass network deserves more …

Novel crystalline transformation of Al polycation sulfates from tetrahedral to block shape was
observed spontaneously in aqueous solution. Theoretical calculations revealed that the …

We present a way of stabilizing cationic partially hydrolyzed aluminum clusters in a non-
acidic environment, through Ca2+ and L-Arginine doping. The Keggin Al13-mer (ε-AlO4Al12 …