Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …

Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

Transition metal catalysis is of utmost importance for the development of sustainable
processes in academia and industry. The activity and selectivity of metal complexes are …

Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …

Abstract Transition-metal-catalysed, non-enzymatic transformations of C–H and C= C bonds
to C–N bonds through nitrene transfer (NT) are powerful synthetic tools to prepare valuable …

The past decade has seen unprecedented growth in the development of new chemical
methods that proceed by mechanisms involving radical intermediates. This new attention …

Enantioselective transition metal catalysis is an area very much at the forefront of
contemporary synthetic research. The development of processes that enable the efficient …

Conspectus Asymmetric functionalization of alkyl radicals represents a robust yet
underdeveloped method for efficient construction and decoration of carbon skeletons in …

Over the past few years, the development of efficient methods to construct high‐valued N‐
heterocyclic molecules have received massive attention owing to their extensive application …

Abstract α-Amino acids are essential for life as building blocks of proteins and components
of diverse natural molecules. In both industry and academia, the incorporation of unnatural …