1. INTRODUCTION Fluorine is the most abundant halogen in the Earth, s crust. 1 However,
only a dozen fluorinated organic compounds have been identified in nature. 2 Most of the …

Abstract Sodium trifluoromethanesulfinate, CF 3 SO 2 Na, and trifluoromethanesulfonyl
chloride, CF 3 SO 2 Cl, are two popular reagents that are widely used for the direct …

This account reviews synthetic strategies for constructing and transforming CF3S (O)
structural moiety developed during the last decades. Existing paths to the synthesis of CF3S …

Defining cellular processes relies heavily on elucidating the temporal dynamics of proteins.
To this end, mass spectrometry (MS) is an extremely valuable tool; different MS-based …

A simple method for the preparation of allylic triflones from allenes and triflyl chloride in the
presence of (EtO) 2P (O) H has been developed. The features of this reaction are catalyst …

The electrophilic thiolation of alkenes initiated by DMTSM and the addition of CF 3 SO 2 Na
in one pot has been developed. This reaction also can be extended to ArSO 2 Na. This …

In this communication, an unprecedented interception of CnF2n+ 1 (O) SO. radical with a
copper‐based carbene has been established. Distinguished by wide substrate scopes and …

The synthesis of various triflones has been achieved using electrophilic
trifluoromethylthiolation reagents as building blocks, and not as reagents …

The use of sulfones as electron-withdrawing groups in substrates for palladium-catalyzed
decarboxylative allylation was explored. A previously published trifluoromethanesulfonyl …

Electrospray ionization mass spectrometry has long been the standard and most prevalent
ionization method in mass spectrometry to detect and analyze molecules of low volatility that …