Near-infrared dyes for two-photon absorption in the short-wavelength infrared: strategies towards optical power limiting

S Pascal, S David, C Andraud, O Maury - Chemical Society Reviews, 2021 - pubs.rsc.org
This work provides an overview of the recent advances in the field of two-photon absorbing
chromophores active in the short-wavelength infrared (SWIR) spectral range. Herein the …

Chemistry of meso-Aryl-Substituted Expanded Porphyrins: Aromaticity and Molecular Twist

T Tanaka, A Osuka - Chemical reviews, 2017 - ACS Publications
Since the discovery of its facile synthesis in 2001, meso-aryl-substituted expanded
porphyrins have been developed as a new class of azaannulenes in light of their facile …

Creation from Confusion and Fusion in the Porphyrin World─ The Last Three Decades of N-Confused Porphyrinoid Chemistry

M Toganoh, H Furuta - Chemical Reviews, 2022 - ACS Publications
Confusion is a novel concept of isomerism in porphyrin chemistry, delivering a steady
stream of new chemistry since the discovery of N-confused porphyrin, a porphyrin mutant, in …

Flexible porphyrinoids

B Szyszko, MJ Białek, E Pacholska-Dudziak… - Chemical …, 2017 - ACS Publications
This review underscores the conformational flexibility of porphyrinoids, a unique class of
functional molecules, starting from the smallest triphyrins (1.1. 1) via [18] porphyrins (1.1 …

Expanded, contracted, and isomeric porphyrins: Theoretical aspects

J Mack - Chemical Reviews, 2017 - ACS Publications
The use of cyclic polyene perimeter-model approaches, such as Gouterman's four-orbital
model and Michl's perimeter model, to analyze trends in the electronic structures and optical …

Carbaporphyrinoid systems

TD Lash - Chemical reviews, 2017 - ACS Publications
Following immediately after the serendipitous discovery of N-confused porphyrins,
remarkably diverse carbaporphyrinoid systems have been synthesized and investigated. By …

Porphyrinoids as a platform of stable radicals

D Shimizu, A Osuka - Chemical Science, 2018 - pubs.rsc.org
The non-innocent ligand nature of porphyrins was observed for compound I in enzymatic
cycles of cytochrome P450. Such porphyrin radicals were first regarded as reactive …

Highly stable neutral corrole radical: amphoteric aromatic–antiaromatic switching and efficient photothermal conversion

H Gao, F Wu, Y Zhao, X Zhi, Y Sun… - Journal of the American …, 2022 - ACS Publications
The preparation of novel stable radical systems that survive and may be manipulated under
harsh conditions is essential for their practical applications, such as energy storage and …

Two-photon absorption: an open door to the NIR-II biological window?

PA Shaw, E Forsyth, F Haseeb, S Yang… - Frontiers in …, 2022 - frontiersin.org
The way in which photons travel through biological tissues and subsequently become
scattered or absorbed is a key limitation for traditional optical medical imaging techniques …

Coordination chemistry of expanded porphyrins

A Alka, VS Shetti, M Ravikanth - Coordination Chemistry Reviews, 2019 - Elsevier
Expanded porphyrins are a class of porphyirinoid macrocycles possessing more than four
pyrrole/other heterocyclic rings and multiple meso-carbon bridges in their conjugated …