F Ortu - Chemical Reviews, 2022 - ACS Publications
The number of rare earth (RE) starting materials used in synthesis is staggering, ranging from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl …
AH Vincent, YL Whyatt, NF Chilton… - Journal of the American …, 2023 - ACS Publications
Substituted dysprosocenium complexes of the type [Dy (Cp R) 2]+ exhibit slow magnetic relaxation at cryogenic temperatures and have emerged as top-performing single-molecule …
The origin of 60 K magnetic hysteresis in the dysprosocenium complex [Dy (Cpttt) 2][B (C6F5) 4](Cpttt= C5H2tBu3-1, 2, 4, 1-Dy) remains mysterious, thus we envisaged that …
RM Diaz-Rodriguez, DA Gálico… - Journal of the …, 2022 - ACS Publications
Lanthanide-based luminescent materials have unique properties and are well-studied for many potential applications. In particular, the characteristic 5d→ 4f emission of divalent …
S Schäfer, S Kaufmann, ES Rösch… - Chemical Society …, 2023 - pubs.rsc.org
Since the discovery in the early 1980s, the soluble divalent metallocenes of lanthanides have become a steadily growing field in organometallic chemistry. The predominant part of …
CAP Goodwin - Dalton Transactions, 2020 - pubs.rsc.org
Progress in the synthesis, design, and characterisation of single-molecule magnets (SMMs) has expanded dramatically from curiosity driven beginnings to molecules that retain …
M Xemard, S Zimmer, M Cordier, V Goudy… - Journal of the …, 2018 - ACS Publications
The Article presents the synthesis, structure, and bonding of a series of neutral and linear sandwich compounds with the cyclononatetraenyl (Cnt) ligand and divalent lanthanides …
At the dawn of the development of structural organometallic chemistry, soon after the discovery of ferrocene, the description of the LnCp3 complexes, featuring large and mostly …
H Wang, LP Zhou, Y Zheng, K Wang… - Angewandte …, 2021 - Wiley Online Library
Supramolecular cages/vesicles in biology display sophisticated structures and functions by utilizing a few types of protein subunit quasi‐equivalently at distinct geometrical locations …