Recent advances in the development of responsive probes for selective detection of cysteine

R Zhang, J Yong, J Yuan, ZP Xu - Coordination Chemistry Reviews, 2020 - Elsevier
Cysteine (Cys), one of three endogenous biothiols, is involved in a variety of biological
processes, such as protein and peptide biosynthesis, enzyme active sites and cofactors, and …

Rare earth starting materials and methodologies for synthetic chemistry

F Ortu - Chemical Reviews, 2022 - ACS Publications
The number of rare earth (RE) starting materials used in synthesis is staggering, ranging
from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl …

Strong axiality in a dysprosium (III) bis (borolide) complex leads to magnetic blocking at 65 K

AH Vincent, YL Whyatt, NF Chilton… - Journal of the American …, 2023 - ACS Publications
Substituted dysprosocenium complexes of the type [Dy (Cp R) 2]+ exhibit slow magnetic
relaxation at cryogenic temperatures and have emerged as top-performing single-molecule …

Synthesis and electronic structures of heavy lanthanide metallocenium cations

CAP Goodwin, D Reta, F Ortu, NF Chilton… - Journal of the …, 2017 - ACS Publications
The origin of 60 K magnetic hysteresis in the dysprosocenium complex [Dy (Cpttt) 2][B
(C6F5) 4](Cpttt= C5H2tBu3-1, 2, 4, 1-Dy) remains mysterious, thus we envisaged that …

Toward opto-structural correlation to investigate luminescence thermometry in an organometallic Eu (II) complex

RM Diaz-Rodriguez, DA Gálico… - Journal of the …, 2022 - ACS Publications
Lanthanide-based luminescent materials have unique properties and are well-studied for
many potential applications. In particular, the characteristic 5d→ 4f emission of divalent …

Divalent metallocenes of the lanthanides–a guideline to properties and reactivity

S Schäfer, S Kaufmann, ES Rösch… - Chemical Society …, 2023 - pubs.rsc.org
Since the discovery in the early 1980s, the soluble divalent metallocenes of lanthanides
have become a steadily growing field in organometallic chemistry. The predominant part of …

Blocking like it's hot: a synthetic chemists' path to high-temperature lanthanide single molecule magnets

CAP Goodwin - Dalton Transactions, 2020 - pubs.rsc.org
Progress in the synthesis, design, and characterisation of single-molecule magnets (SMMs)
has expanded dramatically from curiosity driven beginnings to molecules that retain …

Lanthanidocenes: synthesis, structure, and bonding of linear sandwich complexes of lanthanides

M Xemard, S Zimmer, M Cordier, V Goudy… - Journal of the …, 2018 - ACS Publications
The Article presents the synthesis, structure, and bonding of a series of neutral and linear
sandwich compounds with the cyclononatetraenyl (Cnt) ligand and divalent lanthanides …

Back to the future of organolanthanide chemistry

N Mahieu, J Piątkowski, T Simler, G Nocton - Chemical Science, 2023 - pubs.rsc.org
At the dawn of the development of structural organometallic chemistry, soon after the
discovery of ferrocene, the description of the LnCp3 complexes, featuring large and mostly …

Double‐layered supramolecular prisms self‐assembled by geometrically non‐equivalent tetratopic subunits

H Wang, LP Zhou, Y Zheng, K Wang… - Angewandte …, 2021 - Wiley Online Library
Supramolecular cages/vesicles in biology display sophisticated structures and functions by
utilizing a few types of protein subunit quasi‐equivalently at distinct geometrical locations …