Metal carboxylates with open architectures

CNR Rao, S Natarajan… - Angewandte Chemie …, 2004 - Wiley Online Library
The field of inorganic open‐framework materials is dominated by aluminosilicates and
phosphates. The metal carboxylates have emerged as an important family in the last few …

Synthesis of 3d Metallic Single-Molecule Magnets

G Aromí, EK Brechin - Single-molecule magnets and related phenomena, 2006 - Springer
The phenomenon of single-molecule magnetism was established in the early 1990s with the
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …

[图书][B] The magnetocaloric effect and its applications

AM Tishin, YI Spichkin - 2016 - taylorfrancis.com
The magnetocaloric effect describes the change in temperature of a magnetic material under
adiabatic conditions through the application or removal of an external magnetic field. This …

From Cubane to Supercubane: The Design, Synthesis, and Structure of a Three‐Dimensional Open Framework Based on a Ln4O4 Cluster

BQ Ma, DS Zhang, S Gao, TZ Jin, CH Yan… - Angewandte …, 2000 - Wiley Online Library
Dreidimensionale Kanäle durchziehen ein Netz aus {[Dy 4 (OH) 4 (asp) 3 (H 2 O) 8](ClO 4)
2⋅ 10 H 2 O}-Clustern (siehe Bild). Die Synthese gelang aus Dy (ClO 4) 3 und L …

The Importance of Being Exchanged: [GdIII4MII8(OH)8(L)8(O2CR)8]4+ Clusters for Magnetic Refrigeration

TN Hooper, J Schnack, S Piligkos… - Angewandte Chemie …, 2012 - Wiley Online Library
One of the most promising applications for molecules built from paramagnetic metal ions is
low-temperature magnetic refrigeration.[1] Indeed, recent studies have suggested that …

A New Inorganic−Organic Photoluminescent Material Constructed with Helical [Zn3(μ3-OH)(μ2-OH)] Chains

J Tao, JX Shi, ML Tong, XX Zhang… - Inorganic Chemistry, 2001 - ACS Publications
A photoluminescent inorganic− organic material formulated as [Zn3 (μ 3-OH)(μ 2-OH)(4, 4 '-
bpy) 0.5 (4, 4 '-oba) 2]⊙ 0.5 H2O (4, 4 '-bpy= 4, 4 '-bipyridine; 4, 4 '-oba= 4, 4 '-oxybis …

Cluster-based single-molecule magnets

CJ Milios, REP Winpenny - Molecular Nanomagnets and Related …, 2015 - Springer
This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …

The molecular approach to nanoscale magnetism

A Caneschi, D Gatteschi, C Sangregorio… - Journal of magnetism …, 1999 - Elsevier
Molecular clusters of paramagnetic metal ions have been widely investigated as model for
magnetism at the nanoscale, especially for quantum effects like the tunneling of the …

Studies of a nickel-based single molecule magnet: resonant quantum tunnelling in an S= 12 molecule

C Cadiou, M Murrie, C Paulsen, V Villar… - Chemical …, 2001 - pubs.rsc.org
Studies of a nickel-based single molecule magnet: resonant quantum tunnelling in an S = 12
molecule - Chemical Communications (RSC Publishing) DOI:10.1039/B108894G Royal …

Synthesis of single-molecule magnets using metallocyanates

JN Rebilly, T Mallah - Single-Molecule Magnets and Related Phenomena, 2006 - Springer
Cyanometallate building blocks are inert and stable molecules that may act as ligands
towards metal complexes. A stepwise approach allows preparing polynuclear complexes …