Detection and Identification of the Keto-Hydroperoxide (HOOCH2OCHO) and Other Intermediates during Low-Temperature Oxidation of Dimethyl Ether
K Moshammer, AW Jasper… - The Journal of …, 2015 - ACS Publications
In this paper we report the detection and identification of the keto-hydroperoxide
(hydroperoxymethyl formate, HPMF, HOOCH2OCHO) and other partially oxidized …
(hydroperoxymethyl formate, HPMF, HOOCH2OCHO) and other partially oxidized …
Experimental and kinetic modeling study of the low-and intermediate-temperature oxidation of dimethyl ether
Recent experiments on low-temperature oxidation of dimethyl ether (DME) at atmospheric
pressure reveal much lower fuel conversion than the predictions of all published models …
pressure reveal much lower fuel conversion than the predictions of all published models …
Photodissociation and photoionization of molecules of astronomical interest-Updates to the Leiden photodissociation and photoionization cross section database
HR Hrodmarsson, EF Van Dishoeck - Astronomy & Astrophysics, 2023 - aanda.org
Context. Vacuum-ultraviolet (VUV) photons are important drivers of chemical processes in
space. Thus, it is important to accurately characterize and constrain photorates in different …
space. Thus, it is important to accurately characterize and constrain photorates in different …
High-pressure pyrolysis and oxidation of DME and DME/CH4
H Hashemi, JM Christensen, P Glarborg - Combustion and Flame, 2019 - Elsevier
The pyrolysis and oxidation of dimethyl ether (DME) and its mixture with methane were
investigated at high pressure (50 and 100 bar) and intermediate temperature (450–900 K) …
investigated at high pressure (50 and 100 bar) and intermediate temperature (450–900 K) …
Flame structure and kinetic studies of carbon dioxide-diluted dimethyl ether flames at reduced and elevated pressures
The flame structure and kinetics of dimethyl ether (DME) flames with and without CO 2
dilution at reduced and elevated pressures were studied experimentally and …
dilution at reduced and elevated pressures were studied experimentally and …
Thermal dissociation and roaming isomerization of nitromethane: experiment and theory
CJ Annesley, JB Randazzo… - The Journal of …, 2015 - ACS Publications
The thermal decomposition of nitromethane provides a classic example of the competition
between roaming mediated isomerization and simple bond fission. A recent theoretical …
between roaming mediated isomerization and simple bond fission. A recent theoretical …
Probing combustion chemistry in a miniature shock tube with synchrotron VUV photo ionization mass spectrometry
Tunable synchrotron-sourced photoionization time-of-flight mass spectrometry (PI-TOF-MS)
is an important technique in combustion chemistry, complementing lab-scale electron impact …
is an important technique in combustion chemistry, complementing lab-scale electron impact …
A short reaction mechanism for the combustion of dimethyl-ether
JC Prince, FA Williams - Combustion and Flame, 2015 - Elsevier
Fourteen chemical-kinetic steps are identified, and their associated reaction-rate parameters
are given, that enable an existing short chemical-kinetic mechanism (the San Diego …
are given, that enable an existing short chemical-kinetic mechanism (the San Diego …
A miniature high repetition rate shock tube
RS Tranter, PT Lynch - Review of Scientific Instruments, 2013 - pubs.aip.org
A miniature high repetition rate shock tube with excellent reproducibility has been
constructed to facilitate high temperature, high pressure, gas phase experiments at facilities …
constructed to facilitate high temperature, high pressure, gas phase experiments at facilities …
The role of methyl radical in soot formation
A Eremin, E Mikheyeva - Combustion science and technology, 2019 - Taylor & Francis
It was noted a significant increase in soot formation with the addition of methane in the
pyrolysis of acetylene in shock tubes. Qualitative kinetic analysis revealed an increase of …
pyrolysis of acetylene in shock tubes. Qualitative kinetic analysis revealed an increase of …