Stabilization of transition metals in unusually low coordination numbers, in particular two-or
quasi-two-coordinated metal centers is a challenging area of interest in coordination …

Single-molecule magnets (SMMs) with d7 electronic configurations often require designer
ligands to satisfy the metals electronic conditions to achieve large angular momentum …

A rational approach to modulating easy‐axis magnetic anisotropy by varying the axial donor
ligand in heptacoordinated FeII complexes has been explored. In this series of complexes …

We present the syntheses of trigonal planar coordinated Fe (II) carbodiphosphorane (CDPR)
complexes, starting from iron (II)-bis (trimethylsilylamide)[Fe {N (SiMe3) 2} 2] and …

Iron terminal imido species are typically implicated as reaction intermediates in iron-
catalyzed transformations. While a large body of work has been devoted to mid-and high …

We report an easily prepared bis (thioether) amine ligand, S Me NHS Me, along with the
synthesis, characterization, and reactivity of the paramagnetic iron (II) bis (amido) …

The performance of thermal energy storage systems with Ca (NO 3) 2• 4H 2 O (abbreviated
as CaNT) as a phase change material is limited by its complex thermal properties and …

The reduction of Mn {C (SiMe3) 3} 2 with KC8 in the presence of crown ethers yielded the
d6, Mn (I) salts [K2 (18-crown-6) 3][Mn {C (SiMe3) 3} 2] 2 and [K (15-crown-5) 2][Mn {C …

Ene-amides have been explored as ligands and substrates for oxidative coupling. Treatment
of CrCl2, Cl2Fe (PMe3) 2, and Cl2Copy4 with 2 equiv of {(2, 6-iPr2C6H3)(1-cHexenyl) N} Li …

Transition metal (TM) complexes exhibit diverse structural and electronic properties. The
properties of a TM complex can be tuned by modulating the ligand field strength (LFS) …