Magnetic Molecules as Building Blocks for Quantum Technologies

E Moreno‐Pineda… - Advanced Quantum …, 2024 - Wiley Online Library
Since the initial observation of quantum effects, scientists have worked diligently to
understand and harness their potential. Thanks to many pioneers, a level where quantum …

Magnetic behaviour of a spin-canted asymmetric lanthanide quinolate trimer

L Batista, S Paul, C Molina-Jirón, JA Jaén… - Dalton …, 2024 - pubs.rsc.org
An asymmetrical dysprosium trimer with a molecular formula of [Dy3 (hq) 7 (hqH)(NO3) 2
(H2O)] was obtained through a reflux reaction employing as starting material Dy (NO3) 3 …

Slow magnetic relaxation and strong magnetic coupling in the nitroxyl radical complexes of lanthanide (iii) with diamagnetic ground state (Ln= Lu, Eu)

L Sorace, AA Dmitriev, M Perfetti, KE Vostrikova - Chemical Science, 2025 - pubs.rsc.org
Radical lanthanide complexes are appealing platforms to investigate the possibility to
engineer relevant magnetic couplings between the two magnetic centers by exploiting the …

Enhancement of Single‐Molecule Magnet Properties by Manipulating Intramolecular Dipolar Interactions

JQ Huang, QW Chen, YS Ding, XF Zhu… - Advanced …, 2025 - Wiley Online Library
A new single‐molecule magnet (SMM) complex [K (18‐crown‐6)][(COT) Er (µ‐Cl) 3Er
(COT)](Er2Cl3, COT= cyclooctatetraenide dianion) is obtained by the reaction of [(COT) Er (µ …

Fine-Tuning of Magnetic Anisotropy in Tetranuclear M2Dy2 Complexes with Zig-Zag Topology: The Impact of 3d Metal Selection

GL Lu, ST Chiu, J Long, PH Lin - Crystal Growth & Design, 2024 - ACS Publications
This study presents the design, synthesis, and magnetic characterization of two novel
heterometallic tetranuclear complexes,[M2Dy2 (Hheb) 2 (heb) 4]· 4MeOH (H2heb=(E)-N …

Promoting exchange coupling in (Cp iPr5) 2 Gd 2 X 3 complexes

G David, B Le Guennic, D Reta - Chemical Communications, 2024 - pubs.rsc.org
Introducing magnetic coupling between lanthanide ions has been shown to yield better-
performing single-molecule magnets (SMMs), as exemplified by the Cp2iPr5Ln2I3 family of …

Modulating magnetic anisotropy in linear tetranuclear dysprosium (iii) complexes via coordinated anions

GL Lu, ST Chiu, PH Lin, J Long - Dalton Transactions, 2024 - pubs.rsc.org
We report the synthesis, structures, and magnetic properties of two novel linear tetranuclear
complexes with the general formula [Dy4 (Hheb) 2 (heb) 4X2 (MeOH) 4](X−= NO3−, OAc−; …

Synthesis and reduction of [(C 5 H 4 SiMe 3) 2 Ln (μ-OR)] 2 (Ln= La, Ce) complexes: structural effects of bridging alkoxides

AN Brown, JN Kelleher, AM Brown, P Saghy… - Dalton …, 2024 - pubs.rsc.org
Alcoholysis of Cp′ 3Ln (Ln= La, Ce; Cp′= C5H4SiMe3) generate high-yielding (72–97%)
bimetallic LnIII complexes of [Cp′ 2Ln (μ-OR)] 2 [R= Et, iPr, or C6H4-4-tBu]. Single-crystal X …

A rare case of a zero-field single-ion magnet in a cerium (III) pseudo-icosahedral complex

JR Thomas, MJ Giansiracusa, JT Mifsud, RA Mole… - Dalton …, 2025 - pubs.rsc.org
The synthesis and structural characterisation of [Ln (Tp2-Fu) 2] I (1-Ln; Ln= La, Ce, Pr,
Nd)(Tp2-Fu= hydrotris (3-(2′-furyl)-pyrazol-1-yl) borate) have been reported as an …

Origin of large coercivity in charge-ordered lanthanide-free magnets

MS Platunov, AM Platunov - Materialia, 2025 - Elsevier
Lanthanide-based permanent magnets are essential for a wide range of applications, from
nanotechnology to industrial engineering. However, the limited availability and escalating …