Mixed-valence compounds contain an element which, at least in a formal sense, exists in
more than one oxidation state. 1, 2 This is a common phenomenon. Prussian blue, which …

In the Robin and Day classification, mixed-valence systems are characterized as Class I, II
or III depending on the strength of the electronic interaction between the oxidized and …

Conversion of C–H bonds to C–N bonds via C–H amination promises to streamline the
synthesis of nitrogen-containing compounds. Nitrogen-group transfer (NGT) from metal …

The mixed-valence character of a set of six bistriarylamine derivatives with varying π-
electron spacers has been investigated. The distances of triarylamine redox centers vary …

This review summarizes the literature concerning metal complexes of bis (pyrazolyl) alkane
ligands R2C (pzx) 2 and follows a previous article describing the coordination chemistry of …

Compounds that contain a late transition metal-nitrogen multiple bond represent important
reactive intermediate species in many useful organic and inorganic transformations. In order …

Coupling reactions of nitrogen atoms represent elementary steps to many important
heterogeneously catalysed reactions, such as the Haber–Bosch process or the selective …

Interest is high in+ M‐bridge‐M systems that have very low barriers to intramolecular
electron transfer giving M‐bridge‐M+ (“almost delocalized” systems). Hush showed how to …

Irradiation of rhodium (II) azido complex [Rh (N3){N (CHCHP t Bu2) 2}] allowed for the
spectroscopic characterization of the first reported rhodium complex with a terminal nitrido …

Abstract The N N bond of molecular dinitrogen bridging two molybdenum atoms in the
pentamethylcyclopentadienyl molybdenum complexes that bear ferrocenyldiphosphine as …