Reactivity of metal clusters

Z Luo, AW Castleman Jr, SN Khanna - Chemical reviews, 2016 - ACS Publications
We summarize here the research advances on the reactivity of metal clusters. After a simple
introduction of apparatuses used for gas-phase cluster reactions, we focus on the reactivity …

Coinage metal clusters: From superatom chemistry to genetic materials

B Yin, Z Luo - Coordination Chemistry Reviews, 2021 - Elsevier
Building metal materials with well-defined components and the monomer-genetic property is
one of the foremost challenges in chemistry and materials science. In recent years, metal …

Catalytically active single‐atom sites fabricated from silver particles

Z Huang, X Gu, Q Cao, P Hu, J Hao, J Li… - Angewandte Chemie …, 2012 - infona.pl
Silver chains fabricated from supported silver particles were embedded in Hollandite‐type
manganese oxide, thereby exposing single silver atoms as catalytically active sites (see …

A Novel Redox Precipitation to Synthesize Au-Doped α-MnO2 with High Dispersion toward Low-Temperature Oxidation of Formaldehyde

J Chen, D Yan, Z Xu, X Chen, X Chen… - … science & technology, 2018 - ACS Publications
A novel method of redox precipitation was applied for the first time to synthesize a Au-doped
α-MnO2 catalyst with high dispersion of the Au species. Au nanoparticles (NPs) can be …

Gas-phase kinetics and catalytic reactions of small silver and gold clusters

TM Bernhardt - International Journal of Mass Spectrometry, 2005 - Elsevier
Recent work on the chemical reactivity of mass-selected small silver and gold, as well as
binary silver–gold cluster ions in a temperature controlled radio frequency ion trap …

Low-temperature heterogeneous oxidation catalysis and molecular oxygen activation

UJ Etim, P Bai, OM Gazit, Z Zhong - Catalysis Reviews, 2023 - Taylor & Francis
Many natural oxidations are relevant to the origin and running of life but usually proceeded
under mild conditions using molecular oxygen (O2) in the air as the sole oxidant and …

CO oxidation promoted by gold atoms supported on titanium oxide cluster anions

XN Li, Z Yuan, SG He - Journal of the American Chemical Society, 2014 - ACS Publications
Laser ablation generated Au x (TiO2) y O z–(x= 0, 1; y= 2, 3; z= 1, 2) oxide cluster anions
have been mass-selected using a quadrupole mass filter and reacted with CO in a hexapole …

Clusters as model systems for investigating nanoscale oxidation catalysis

GE Johnson, R Mitrić, V Bonačić-Koutecký… - Chemical Physics …, 2009 - Elsevier
Gas-phase cluster reactivity experiments, combined with theoretical calculations, provide
insight into how factors such as size, stoichiometry and charging effects influence reactions …

Spin Accommodation and Reactivity of Silver Clusters with Oxygen: The Enhanced Stability of Ag13

Z Luo, GU Gamboa, JC Smith, AC Reber… - Journal of the …, 2012 - ACS Publications
Spin accommodation is demonstrated to play a determining role in the reactivity of silver
cluster anions with oxygen. Odd-electron silver clusters are found to be especially reactive …

Theoretical exploration of ultrafast dynamics in atomic clusters: Analysis and control

V Bonačić-Koutecký, R Mitrić - Chemical reviews, 2005 - ACS Publications
Theoretical investigations of femtosecond dynamical processes in elemental clusters and
their active control by designed light fields are of fundamental importance for learning how …