Catalysis of alloys: classification, principles, and design for a variety of materials and reactions

Y Nakaya, S Furukawa - Chemical Reviews, 2022 - ACS Publications
Alloying has long been used as a promising methodology to improve the catalytic
performance of metallic materials. In recent years, the field of alloy catalysis has made …

Gold-catalyzed carbon− heteroatom bond-forming reactions

A Corma, A Leyva-Pérez, MJ Sabater - Chemical reviews, 2011 - ACS Publications
After the long-held assumption of the unreactivity of gold, numerous reactions catalyzed by
this noble metal have been increasingly emerging in the literature over the past 2 decades …

Pd–Au bimetallic catalysts: understanding alloy effects from planar models and (supported) nanoparticles

F Gao, DW Goodman - Chemical Society Reviews, 2012 - pubs.rsc.org
Pd–Au bimetallic catalysts often display enhanced catalytic activities and selectivities
compared with Pd-alone catalysts. This enhancement is often caused by two alloy effects, ie …

Shape-controlled synthesis of Au–Pd bimetallic nanocrystals for catalytic applications

L Zhang, Z Xie, J Gong - Chemical Society Reviews, 2016 - pubs.rsc.org
Au–Pd nanostructured materials have been recognized as important heterogeneous
catalysts in various reactions, due to their superior activities caused by the ensemble and …

Interstitial carbon dopant in palladium–gold alloy boosting the catalytic performance in vinyl acetate monomer synthesis

Y Nakaya, E Hayashida, R Shi, K Shimizu… - Journal of the …, 2023 - ACS Publications
Vinyl acetate monomer (VAM), an important chemical intermediate in industry, is produced
by the well-established commercial process of acetoxylation of ethylene with Pd–Au/SiO2 …

AuPd−Fe3O4 Nanoparticle Catalysts for Highly Selective, One‐Pot Cascade Nitro‐Reduction and Reductive Amination

A Cho, S Byun, BM Kim - Advanced Synthesis & Catalysis, 2018 - Wiley Online Library
Exceedingly chemoselective preparation of secondary amines from the cascade reaction of
nitro reduction followed by reductive amination of the resulting amine with an aldehyde …

Theoretical insight into the effect of impurity on the acetoxylation of ethylene to form vinyl acetate: A DFT study of acetylene coversion on PdAu (1 0 0) surface

W Zhang, J Zhang, Y Yu - Fuel, 2022 - Elsevier
Vinyl acetate (VA) is an important organic chemical material, which is mainly obtained from
ethylene acetoxylation. The raw material, ethylene, usually contains a small amount of …

Atomic ensemble effects on formic acid oxidation on PdAu electrode studied by first-principles calculations

DW Yuan, ZR Liu - Journal of power sources, 2013 - Elsevier
Using first-principles methods, we investigated the reaction pathways of the formic acid
oxidation on Pd (111) and PdAu (111) surfaces. The dehydrogenation of formic acid can …

Electrochemical Pd nanodeposits on a Au nanoisland template supported on Si (100): Formation of Pd− Au alloy and interfacial electronic structures

Y Sohn, D Pradhan, KT Leung - ACS nano, 2010 - ACS Publications
Palladium nanoparticles have uniformly been electrodeposited on a Au nanoisland template
(NIT) supported on a Si (100) substrate, which exhibits Au-rich, Pd-rich, and/or …

Surface-level mechanistic studies of adsorbate–adsorbate interactions in heterogeneous catalysis by metals

ST Marshall, JW Medlin - Surface science reports, 2011 - Elsevier
Despite being considered a mature field, recent developments in experimental and
theoretical techniques have greatly increased the fundamental understanding of complex …