Thermomorphic multiphase systems: switchable solvent mixtures for the recovery of homogeneous catalysts in batch and flow processes

J Bianga, KU Künnemann, T Gaide… - … A European Journal, 2019 - Wiley Online Library
Over the past 20 years, thermomorphic multiphase systems (TMS) have been used as a
versatile and elegant strategy for the recovery and recycling of homogeneous transition …

Hydroformylation of 1-dodecene in the thermomorphic solvent system dimethylformamide/decane. Phase behavior–reaction performance–catalyst recycling

E Schäfer, Y Brunsch, G Sadowski… - Industrial & engineering …, 2012 - ACS Publications
An economically meaningful hydroformylation of long-chain olefins requires an efficient
combination of both a high-yield reaction step and efficient catalyst recycling. The …

Kinetics of 1-dodecene hydroformylation in a thermomorphic solvent system using a rhodium-biphephos catalyst

G Kiedorf, DM Hoang, A Müller, A Jörke… - Chemical Engineering …, 2014 - Elsevier
The hydroformylation of 1-dodecene on a rhodium-biphephos catalyst complex exploiting a
thermomorphic multicomponent solvent system was studied experimentally in a batch …

Temperature-controlled catalyst recycling in homogeneous transition-metal catalysis: minimization of catalyst leaching.

Y Brunsch, A Behr - Angewandte Chemie International …, 2013 - search.ebscohost.com
Reduce–reuse–recycle! One of the challenges in applied homogeneous catalysis is the
efficient recycling of the valuable metal catalyst. The catalyst recycling concept of …

Core–shell nanoreactors for efficient aqueous biphasic catalysis

X Zhang, AF Cardozo, S Chen, W Zhang… - … A European Journal, 2014 - Wiley Online Library
Water‐borne phosphine‐functionalized core‐cross‐linked micelles (CCM) consisting of a
hydrophobic core and a hydrophilic shell were obtained as stable latexes by reversible …

Overcoming Phase‐Transfer Limitations in the Conversion of Lipophilic Oleo Compounds in Aqueous Media—A Thermomorphic Approach

T Gaide, JM Dreimann, A Behr… - Angewandte Chemie …, 2016 - Wiley Online Library
A new process concept has been developed for recycling transition‐metal catalysts in the
synthesis of moderately polar products via aqueous thermomorphic multicomponent solvent …

Toward water-based recycling techniques: methodologies for homogeneous catalyst recycling in liquid/liquid multiphase media and their implementation in …

T Rosler, TA Faßbach, M Schrimpf… - Industrial & …, 2018 - ACS Publications
Biphasic water-based solvent systems offer the opportunity of efficient recycling of
homogeneous catalysts. Water separates well from most organic solvents; therefore, water …

Hydroesterification of methyl 10-undecenoate in thermomorphic multicomponent solvent systems—Process development for the synthesis of sustainable polymer …

T Gaide, A Behr, A Arns, F Benski, AJ Vorholt - Chemical Engineering and …, 2016 - Elsevier
In this paper, we present a process concept for the atom economic hydroesterification of
renewable methyl 10-undecenoate in thermomorphic multicomponent solvent (TMS) …

Selective hydroformylation of olefins over the rhodium supported large porous metal–organic framework MIL-101

T Van Vu, H Kosslick, A Schulz, J Harloff… - Applied Catalysis A …, 2013 - Elsevier
Highly porous and crystalline metal–organic framework MIL-101 has been synthesized and
used for the preparation of rhodium supported catalyst. Acetylacetonato (1, 5 …

Hydroformylation and tandem isomerization–hydroformylation of n-decenes using a rhodium-BiPhePhos catalyst: Kinetic modeling, reaction network analysis and …

A Jörke, T Gaide, A Behr, A Vorholt… - Chemical Engineering …, 2017 - Elsevier
The rhodium-BiPhePhos catalyzed hydroformylation of n-decenes, as representative long-
chain olefins, was investigated in this study experimentally and theoretically. Besides …