Crystallization in thin films of polymer glasses: The role of free surfaces, solid interfaces and their competition

Y Yang, H Tian, S Napolitano, B Zuo - Progress in Polymer Science, 2023 - Elsevier
Polymer coatings of nanometric thickness are about to enter in everyday life as part of a
wide range of applications such as protective layers, stimuli-responsive membranes or as …

Ultrastable glasses: new perspectives for an old problem

C Rodriguez-Tinoco, M Gonzalez-Silveira… - La Rivista del Nuovo …, 2022 - Springer
Ultrastable glasses (mostly prepared from the vapor phase under optimized deposition
conditions) represent a unique class of materials with low enthalpies and high kinetic …

Surface dynamics of glasses

H Tian, Q Xu, H Zhang, RD Priestley, B Zuo - Applied Physics Reviews, 2022 - pubs.aip.org
Two challenging scientific disciplines, ie, the physics of glasses [Anderson, Science 267,
1615 (1995); Kennedy and Norman, Science 309, 75 (2005)] and interface chemistry …

Surface diffusion is controlled by bulk fragility across all glass types

Y Li, A Annamareddy, D Morgan, Z Yu, B Wang… - Physical Review Letters, 2022 - APS
Surface diffusion is vastly faster than bulk diffusion in some glasses, but only moderately
enhanced in others. We show that this variation is closely linked to bulk fragility, a common …

Surface diffusion in glasses of rod-like molecules posaconazole and itraconazole: Effect of interfacial molecular alignment and bulk penetration

Y Li, W Zhang, C Bishop, C Huang, MD Ediger, L Yu - Soft Matter, 2020 - pubs.rsc.org
The method of surface grating decay has been used to measure surface diffusion in the
glasses of two rod-like molecules posaconazole (POS) and itraconazole (ITZ). Although …

What we need to know about solid-state isothermal crystallization of organic molecules from the amorphous state below the glass transition temperature

A Newman, G Zografi - Molecular pharmaceutics, 2020 - ACS Publications
In this Perspective, the authors have examined various principles associated with the
isothermal crystallization of organic molecules from the amorphous state. The major …

Using deposition rate and substrate temperature to manipulate liquid crystal-like order in a vapor-deposited hexagonal columnar glass

C Bishop, Z Chen, MF Toney, H Bock… - The Journal of …, 2021 - ACS Publications
We investigate vapor-deposited glasses of a phenanthroperylene ester, known to form an
equilibrium hexagonal columnar phase, and show that liquid crystal-like order can be …

Vapor-deposited glass structure determined by deposition rate–substrate temperature superposition principle

C Bishop, A Gujral, MF Toney, L Yu… - The journal of physical …, 2019 - ACS Publications
We show that deposition rate substantially affects the anisotropic structure of thin glassy
films produced by physical vapor deposition. Itraconazole, a glass-forming liquid crystal, was …

Recent advances in the application of characterization techniques for studying physical stability of amorphous pharmaceutical solids

Y Wang, Y Wang, J Cheng, H Chen, J Xu, Z Liu, Q Shi… - Crystals, 2021 - mdpi.com
The amorphous form of a drug usually exhibits higher solubility, faster dissolution rate, and
improved oral bioavailability in comparison to its crystalline forms. However, the amorphous …

Role of molecular layering in the enhanced mechanical properties of stable glasses

SE Wolf, S Fulco, A Zhang, H Zhao… - The Journal of …, 2022 - ACS Publications
The density, degree of molecular orientation, and molecular layering of vapor-deposited
stable glasses (SGs) vary with substrate temperature (T dep) below the glass-transition …