Spontaneous deracemizations

T Buhse, JM Cruz, ME Noble-Teran… - Chemical …, 2021 - ACS Publications
Spontaneous deracemizations is a challenging, multidisciplinary subject in current chirality
research. In the absence of any chiral inductors, an achiral substance or a racemic …

Self-sorting phenomena in complex supramolecular systems

MM Safont-Sempere, G Fernández… - Chemical …, 2011 - ACS Publications
Nature successfully manages under extremely adverse conditions to accomplish intricate
functions responsible for the regulation and control of the vast majority of biological …

Chiral templated synthesis of homochiral metal-organic frameworks

K Berijani, LM Chang, ZG Gu - Coordination Chemistry Reviews, 2023 - Elsevier
The concept of chirality has been developed in various industrial and scientific fields such as
chemistry, biology, physics, life and environmental sciences. As known, chiral materials …

Crystalline architectures as templates of relevance to the origins of homochirality

I Weissbuch, M Lahav - Chemical Reviews, 2011 - ACS Publications
From the days of Biot1 and Pasteur, 2 when it was recognized that biopolymers are
composed from residues of a single handedness, scientists were puzzled as to the ancestry …

The RNA world as a model system to study the origin of life

A Pressman, C Blanco, IA Chen - Current Biology, 2015 - cell.com
Understanding how life arose is a fundamental problem of biology. Much progress has been
made by adopting a synthetic and mechanistic perspective on originating life. We present a …

Evolution of solid phase homochirality for a proteinogenic amino acid

C Viedma, JE Ortiz, T Torres, T Izumi… - Journal of the …, 2008 - ACS Publications
The inexorable evolution of solid-phase single chirality is demonstrated for the first time for a
proteinogenic amino acid. Enantioenrichment is observed both under attrition-enhanced …

A highly efficient asymmetric organocatalytic aldol reaction in a ball mill

B Rodríguez, A Bruckmann… - Chemistry–A European …, 2007 - Wiley Online Library
Anti‐aldol products with up to> 99% enantiomeric excess (ee) have been obtained by
proline catalysis in excellent yields under experimentally simple solvent‐free conditions …

From Ostwald ripening to single chirality

WL Noorduin, E Vlieg, RM Kellogg… - Angewandte Chemie …, 2009 - Wiley Online Library
A century ago Wilhelm Ostwald received the Nobel Prize for Chemistry. Although Ostwald
was never significantly involved with the phenomenon of chirality, one of his discoveries …

Using programmed heating–cooling cycles with racemization in solution for complete symmetry breaking of a conglomerate forming system

K Suwannasang, AE Flood, C Rougeot… - Crystal growth & …, 2013 - ACS Publications
A deracemization technique using periodic temperature fluctuations on a conglomerate
forming system undergoing a swift racemization in solution is demonstrated. The method …

The driving mechanism behind attrition‐enhanced deracemization

WL Noorduin, WJP van Enckevort… - Angewandte Chemie …, 2010 - Wiley Online Library
The transformation of the enantiomorphic but intrinsically achiral salt NaClO3 into single
chirality was recently demonstrated by Viedma by simply grinding the crystals in a saturated …