Recent advances in gold (III) chemistry: structure, bonding, reactivity, and role in homogeneous catalysis

L Rocchigiani, M Bochmann - Chemical Reviews, 2020 - ACS Publications
Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Synthetic routes to late transition metal–NHC complexes

T Scattolin, SP Nolan - Trends in Chemistry, 2020 - cell.com
Transition metal complexes bearing N-heterocyclic carbene ligands (NHCs) have gained a
place of crucial importance in numerous areas of research such as medicinal chemistry …

Janus-type emission from a cyclometalated iron(iii) complex

J Steube, A Kruse, OS Bokareva, T Reuter… - Nature Chemistry, 2023 - nature.com
Although iron is a dream candidate to substitute noble metals in photoactive complexes,
realization of emissive and photoactive iron compounds is demanding due to the fast …

Reversible transformations between the non-porous phases of a flexible coordination network enabled by transient porosity

VI Nikolayenko, DC Castell, D Sensharma… - Nature Chemistry, 2023 - nature.com
Flexible metal–organic materials that exhibit stimulus-responsive switching between closed
(non-porous) and open (porous) structures induced by gas molecules are of potential utility …

Reaction Behavior of [1,3-Diethyl-4,5-diphenyl-1H-imidazol-2-ylidene] Containing Gold(I/III) Complexes against Ingredients of the Cell Culture Medium and the …

P Kapitza, A Scherfler, S Salcher… - Journal of Medicinal …, 2023 - ACS Publications
The reactivities of halido [1, 3-diethyl-4, 5-diphenyl-1 H-imidazol-2-ylidene] gold (I)(chlorido
(5), bromido (6), iodido (7)), bis [1, 3-diethyl-4, 5-diphenyl-1 H-imidazol-2-ylidene] gold (I)(8) …

Conceptual advances in the preparation and excited-state properties of neutral luminescent (C^ N) and (C^ C*) monocyclometalated gold (III) complexes

R Malmberg, K Venkatesan - Coordination Chemistry Reviews, 2021 - Elsevier
Luminescent cyclometalated complexes are indispensable in today's technologies and are
applied as emitters in organic light-emitting diode (OLED) devices, photocatalysts …

The Fluoride Method: Access to Silver (III) NHC Complexes

J Pueyo, D Joven‐Sancho, A Martín… - … A European Journal, 2024 - Wiley Online Library
We have synthesized the first silver (III) carbene complexes,(CF3) 3Ag (NHC), by direct
reaction of the silver (III) fluoride precursor complex [PPh4][(CF3) 3AgF] with different …

Role of σ, π-Digold (I) alkyne complexes in reactions of enynes

S Ferrer, AM Echavarren - Organometallics, 2017 - ACS Publications
Gold (I) acetylide and σ, π-digold (I) alkyne complexes derived from one prototypical 1, 6-
enyne and from 7-ethynyl-1, 3, 5-cycloheptatriene have been prepared and structurally …

Synthesis, characterization, and catalytic activities of palladium complexes with phenylene-bridged bis (thione) ligands

WG Jia, LL Gao, ZB Wang, LY Sun, YF Han - Organometallics, 2019 - ACS Publications
The neutral phenylene-bridged bis (thione) compounds, 1, 3-bis (3′-ethylimidazolyl-2′-
thione) benzene (Betb), 1, 3-bis (3′-butylimidazolyl-2′-thione) benzene (Bbtb), and 1, 3 …

Synthesis, Structural Characterization and Antiproliferative Activity of Gold (I) and Gold (III) Complexes Bearing Thioether‐Functionalized N‐Heterocyclic Carbenes

R De Marco, M Dal Grande, M Baron… - European Journal of …, 2021 - Wiley Online Library
A series of gold (I) and gold (III) complexes with N‐heterocyclic carbene ligands
functionalized with a pendant thioether group (NHC‐SR) was synthesized with …