Nickel catalyzed olefin oligomerization and dimerization
H Olivier-Bourbigou, PAR Breuil, L Magna… - Chemical …, 2020 - ACS Publications
Brought to life more than half a century ago and successfully applied for high-value
petrochemical intermediates production, nickel-catalyzed olefin oligomerization is still a very …
petrochemical intermediates production, nickel-catalyzed olefin oligomerization is still a very …
Bridging the Gap between Industrial and Well‐Defined Supported Catalysts
C Copéret, F Allouche, KW Chan… - Angewandte Chemie …, 2018 - Wiley Online Library
Many industrial catalysts contain isolated metal sites on the surface of oxide supports.
Although such catalysts have been used in a broad range of processes for more than 40 …
Although such catalysts have been used in a broad range of processes for more than 40 …
Confined catalysis under two-dimensional materials
Confined microenvironments formed in heterogeneous catalysts have recently been
recognized as equally important as catalytically active sites. Understanding the …
recognized as equally important as catalytically active sites. Understanding the …
Linear α-olefin oligomerization and polymerization catalyzed by metal-organic frameworks
In the industry of petrochemicals, oligomerization of α-olefins, mainly ethylene and
propylene, is an important process that produces linear α-olefins (LAOs). Industrial …
propylene, is an important process that produces linear α-olefins (LAOs). Industrial …
Structure and site evolution of framework Ni species in MIL-127 MOFs for propylene oligomerization catalysis
B Yeh, S Chheda, SD Prinslow… - Journal of the …, 2023 - ACS Publications
A mixed-valence oxotrimer metal–organic framework (MOF), Ni-MIL-127, with a fully
coordinated nickel atom and two iron atoms in the inorganic node, generates a missing …
coordinated nickel atom and two iron atoms in the inorganic node, generates a missing …
Ethene oligomerization in Ni-containing zeolites: theoretical discrimination of reaction mechanisms
RY Brogaard, U Olsbye - Acs Catalysis, 2016 - ACS Publications
Ni-containing porous aluminosilicates are promising heterogeneous catalysts for
oligomerization of ethene, but little is known about the catalytic cycle. In addition, it remains …
oligomerization of ethene, but little is known about the catalytic cycle. In addition, it remains …
Evidence for the coordination–insertion mechanism of ethene dimerization at nickel cations exchanged onto beta molecular sieves
The mechanistic origin of alkene dimerization on Ni sites supported on aluminosilicates has
been ascribed to both coordination–insertion (ie, Cossee-Arlman) and metallacycle-based …
been ascribed to both coordination–insertion (ie, Cossee-Arlman) and metallacycle-based …
Mechanistic insights into alkene chain growth reactions catalyzed by nickel active sites on ordered microporous and mesoporous supports
Alkene oligomerization on heterogeneous Ni-based catalysts has been studied for several
decades, with recent attention focused on the preparation, structure and function of Ni active …
decades, with recent attention focused on the preparation, structure and function of Ni active …
Ethylene oligomerization on nickel catalysts on a solid acid support: From New mechanistic insights to tunable bifunctionality
Light alkene oligomerization on heterogeneous acidic catalysts is widely and successfully
used in current commercial processes. However, ethylene oligomerization remains …
used in current commercial processes. However, ethylene oligomerization remains …
Oligomerization of light olefins over ZSM-5 and beta zeolite catalysts by modifying textural properties
S Moon, HJ Chae, MB Park - Applied Catalysis A: General, 2018 - Elsevier
The oligomerization of ethene and 1-hexene was performed under 35 bar and 200° C over
NiH-and H-forms of ZSM-5 and beta zeolite catalysts which had similar Si/Al and Ni content …
NiH-and H-forms of ZSM-5 and beta zeolite catalysts which had similar Si/Al and Ni content …