Environmentally benign polyoxometalate materials

S Omwoma, CT Gore, Y Ji, C Hu, YF Song - Coordination Chemistry …, 2015 - Elsevier
Polyoxometalates (POMs) are a class of versatile and discrete anionic metal oxides in
groups 5 and 6. POMs have unique physical and chemical properties, eg, strong Brønsted …

Keggin-type lacunary and transition metal substituted polyoxometalates as heterogeneous catalysts: A recent progress

A Patel, N Narkhede, S Singh, S Pathan - Catalysis Reviews, 2016 - Taylor & Francis
In this article we discussed synthesis and catalytic applications of heterogeneous catalysts
based on lacunary polyoxometalates (LPOMs) and transition metal substituted …

Direct synthesis of mesoporous SRL-POM@ MOF-199@ MCM-41 and its highly catalytic performance for the oxidesulfurization of DBT

SW Li, Z Yang, RM Gao, G Zhang, J Zhao - Applied Catalysis B …, 2018 - Elsevier
With the increasing aim of deep desulfurization of fuel, a kind of novel surfactant-type
heteropolyacid [(CH 3) 2 (C n H 2n+ 1) N (CH 2)] 2 [POM](SRL-POM, n= 10, 12, 14 and 16) …

Synthesis of new nanocomposite based on nanoceramic and mono substituted polyoxometalate, PMo11Cd@MnFe2O4, with superior catalytic activity for oxidative …

MA Rezvani, M Hadi, SA Mirsadri - Applied Organometallic …, 2020 - Wiley Online Library
In this manuscript, a novel nanocomposite PMo11CdO39@ MnFe2O4 (PMo11Cd@
MnFe2O4) based on ceramic (MnFe2O4) and mono substitute polyoxometalate (PMo11Cd) …

Confining polyoxometalate clusters into porous aromatic framework materials for catalytic desulfurization of dibenzothiophene

P Wang, L Jiang, X Zou, H Tan, P Zhang… - … applied materials & …, 2020 - ACS Publications
Removal of notorious sulfur compounds to produce low-sulfur-content (≤ 10 ppm) diesel is
necessary and vital for modern industry and environmental protection. A new type of …

Direct synthesis of mesoporous H3PMo12O40/SiO2 and its catalytic performance in oxidative desulfurization of fuel oil

J Qiu, G Wang, Y Zhang, D Zeng, Y Chen - Fuel, 2015 - Elsevier
Mesoporous silica materials incorporated with phosphomolybdic acid (HPMo) have been
prepared by the precipitation method and investigated on their oxidative desulfurization of …

Oxidative desulfurization strategies using Keggin-type polyoxometalate catalysts: Biphasic versus solvent-free systems

SO Ribeiro, CM Granadeiro, PL Almeida, J Pires… - Catalysis today, 2019 - Elsevier
Strategic polyoxometalate Keggin-type structural modification was performed to increase the
oxidative catalytic performance to desulfurize model and real diesels. The most active …

Heteropolyacid supported MOF fibers for oxidative desulfurization of fuel

J Li, Z Yang, G Hu, J Zhao - Chemical Engineering Journal, 2020 - Elsevier
Three methods are tried to synthesize a novel type of inorganic-organic hybrid catalyst
(HPA@ MOF@ CA) for oxidative desulfurization by the composition of phosphomolybdenum …

[HTML][HTML] Highly active phosphotungstic acid immobilized on amino functionalized MCM-41 for the oxidesulfurization of dibenzothiophene

G Luo, L Kang, M Zhu, B Dai - Fuel processing technology, 2014 - Elsevier
Abstract Phosphotungstic acid H 3 PW 12 O 40 (HPW) was successfully immobilized on the
surface of MCM-41 functionalized with amino groups. The obtained catalysts were …

Heteropolyacids supported on macroporous materials POM@ MOF-199@ LZSM-5: Highly catalytic performance in oxidative desulfurization of fuel oil with oxygen

SW Li, RM Gao, W Zhang, Y Zhang, J Zhao - Fuel, 2018 - Elsevier
A highly active catalyst Keggin type POM-based inorganic-organic compound POM@ MOF-
199@ LZSM-5 (PMZ) has been prepared and applied in the catalytic oxidative …