Anionic conjugate additions are one of the most important carbon-carbon bond-forming
reactions in organic synthesis. 1 The maturity of conjugate addition reactions is attested by …

This review covers literature on non-stabilized functionalized organolithium compounds
since 1997. In this overview, we consider intermediates with different separation between …

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Service Library Service Help Contact Portal SynOpen Full-text search Full-text search Author …

Abstract The B (C6F5) 3‐catalyzed silylative reduction of conjugated nitriles has been
developed to afford synthetically valuable β‐silyl amines. The reaction is chemoselective …

The first example of an organocatalytic enantioselective conjugate addition of cyclic β-
ketoesters and glycine imine derivatives to electron-deficient allenes is described. We …

The stereoselective preparation of (E)-or (Z)-trisubstituted α, β-unsaturated esters in three
steps from N-protected glycine is presented. The key step in the synthesis is the highly …

Highly Selective 1,6-Addition of Aryl Boronic Acids to α,β,γ,δ-Unsaturated Carbonyl Compounds
Catalyzed by an Iridium Complex Organic Chemistry Portal Abstracts Search: Highly Selective …

Copper salts have been screened for transmetalation and electrophilic quench of N-tert-
butoxycarbonyl-2-lithiopyrrolidine (N-Boc-2-lithiopyrrolidine) and N-Boc-2-lithiopiperidine …

Olefins, compounds with a carbon–carbon double bond, are of fundamental importance, and
stereodefined construction of tetrasubstituted carbon–carbon double bond is a significant …

Although significant progress has been made in asymmetric organocopper reactions
employing chiral anionic (eg, RCuL* Li) or neutral nontransferable heteroatom ligands …