Reaction induced self-separating metal catalysts–Wonder systems in 21st century catalysis
P Neves, DM Gomes, IS Gonçalves, M Pillinger… - Coordination Chemistry …, 2023 - Elsevier
The term Catalysis was first coined in the 19th century and has since been recognized as a
fundamental field contributing to the greenness and sustainability of chemical processes …
fundamental field contributing to the greenness and sustainability of chemical processes …
Molybdenum (VI) dioxo complexes employing Schiff base ligands with an intramolecular donor for highly selective olefin epoxidation
ME Judmaier, C Holzer, M Volpe… - Inorganic …, 2012 - ACS Publications
Reaction of [MoO2 (η2-t Bu2pz) 2] with Schiff base ligands HLX (X= 1–5) gave molybdenum
(VI) dioxo complexes of the type cis-[MoO2 (LX) 2] as yellow to light brown solids in …
(VI) dioxo complexes of the type cis-[MoO2 (LX) 2] as yellow to light brown solids in …
Solvent‐Free Epoxidation of Olefins Catalyzed by “[MoO2(SAP)]”: A New Mode of tert‐Butylhydroperoxide Activation
The mononuclear molybdenum complexes [MoO2 (acac) 2](1, acac= acetylacetonate),[
MoO2 (SAP)(MeOH)](2), and dinuclear oxomolybdic complexes [MoO2L] 2 [L …
MoO2 (SAP)(MeOH)](2), and dinuclear oxomolybdic complexes [MoO2L] 2 [L …
Olefin Epoxidation by H2O2/MeCN Catalysed by Cyclopentadienyloxidotungsten(VI) and Molybdenum(VI) Complexes: Experiments and Computations
C Dinoi, M Ciclosi, E Manoury, L Maron… - … A European Journal, 2010 - Wiley Online Library
Abstract Compounds [Cp* 2M2O5](M= Mo, 1; W, 2) are efficient pre‐catalysts for cyclooctene
(COE) epoxidation by aqueous H2O2 in acetonitrile/toluene. The reaction is quantitative …
(COE) epoxidation by aqueous H2O2 in acetonitrile/toluene. The reaction is quantitative …
Mechanism of Al3+-Catalyzed Oxidations of Hydrocarbons: Dramatic Activation of H2O2 toward O−O Homolysis in Complex [Al(H2O)4(OOH)(H2O2)]2+ Explains the …
ML Kuznetsov, YN Kozlov, D Mandelli… - Inorganic …, 2011 - ACS Publications
A radical mechanism of hydrocarbon oxidations with the environmentally friendly and cheap
homogeneous nontransition metal system [Al (H2O) 6] 3+/H2O2/MeCN− H2O was proposed …
homogeneous nontransition metal system [Al (H2O) 6] 3+/H2O2/MeCN− H2O was proposed …
Molecular epoxidation reactions catalyzed by rhenium, molybdenum, and iron complexes
JW Kück, RM Reich, FE Kühn - The Chemical Record, 2016 - Wiley Online Library
Epoxidations are of high relevance in many organic syntheses, both in industry and
academia. In this personal account, the development of rhenium, molybdenum, and iron …
academia. In this personal account, the development of rhenium, molybdenum, and iron …
Organometallic Compounds for Epoxidation Chemistry: a brief insight into research developments
FE Kühn - Journal of Organometallic Chemistry, 2023 - Elsevier
Catalytic epoxidation reactions are an important area in chemical industries. Since the
1960s high oxidation transition metal complexes have been examined and applied as …
1960s high oxidation transition metal complexes have been examined and applied as …
Dioxo and oxo-peroxo molybdenum (VI) complexes bearing salicylidene 2-picoloyl hydrazone: Structures and catalytic performances
Molybdenum complexes bearing a salicylidene 2-picoloyl hydrazone ligand have been
synthesized and characterized. The salicylidene 2-picoloyl hydrazone ligand (H2sal-phz) …
synthesized and characterized. The salicylidene 2-picoloyl hydrazone ligand (H2sal-phz) …
Immobilisation of a molecular epoxidation catalyst on UiO-66 and-67: the effect of pore size on catalyst activity and recycling
M Kaposi, M Cokoja, CH Hutterer, SA Hauser… - Dalton …, 2015 - pubs.rsc.org
Amino-functionalised metal–organic frameworks UiO-66 and-67 were post-synthetically
modified with salicylaldehyde. A molybdenum complex was immobilised on the resulting …
modified with salicylaldehyde. A molybdenum complex was immobilised on the resulting …
Pyridoxal based ONS and ONO vanadium (V) complexes: Structural analysis and catalytic application in organic solvent free epoxidation
A series of dinuclear and mononuclear oxovanadium (V) complexes containing tridentate
Schiff base ligands derived from pyridoxal and appropriate thiosemicarbazide or hydrazide …
Schiff base ligands derived from pyridoxal and appropriate thiosemicarbazide or hydrazide …