Hydration shells of ions are dynamical structures showing (deformation) vibrations and
rotations. In addition, water molecules are continuously being exchanged between the shell …

Applications of 2D IR Spectroscopy to Peptides, Proteins, and Hydrogen-Bond Dynamics | The
Journal of Physical Chemistry B ACS ACS Publications C&EN CAS Find my institution Log In …

In this chapter the fundamental problem of transfer and dissipation of vibrational energy in
liquids is investigated on a microscopic level. Vibrational excess energy may appear locally …

Measurements of the nonlinear dispersion of χ (3) have been performed on the surface
plasmon resonance of aqueous colloidal gold. An analysis of the observed dispersion has …

The vibrational relaxation time of the cyanide ion in H 2 O and in D 2 O was measured by IR-
pump–IR-probe experiments. The isotopic composition of the ion was varied in order vary …

This paper presents the first application of semiclassical methodology to the calculation of
vibrational energy relaxation (VER) rate constants in condensed phase systems. The VER …

The vibrational energy relaxation of a model methyl chloride molecule in water is studied
through equilibrium and nonequilibrium molecular dynamics simulations. Previous work …

Infrared pump–probe and infrared polarization spectroscopy have been used to measure
the vibrational relaxation times (T 1) of the antisymmetric stretching mode and the …

Classical molecular dynamics simulations complemented with semiclassical perturbation
theory have been applied to the study of the cyanide ion vibrational relaxation in liquid …

A microscopic statistical mechanical theory of the vibrational energy relaxation of a diatomic
solute in an atomic solvent is presented. The diatomic is treated as a breathing Lennard …