Xanthates routes to sulfur-containing heterocycles

F Gholami, S Ansari, B Larijani, M Mahdavi - Journal of Organometallic …, 2023 - Elsevier
Sulfur-containing heterocycles, due to their application in material science, biology, and
pharmaceutics, have great importance. Although different sulfurating agents have been …

Recent metal-catalyzed methods for thioether synthesis

VJ Geiger, RM Oechsner, PH Gehrtz, I Fleischer - Synthesis, 2022 - thieme-connect.com
This review summarizes the more recent methods (since 2015) for the synthesis of
thioethers using homogeneous metals as catalysts. The thioether moiety can be found in …

Synthetic exploration of electrophilic xanthylation via powerful N-xanthylphthalimides

S Wang, L Yang, F Liang, Y Zhong, X Liu, Q Wang… - Chemical …, 2023 - pubs.rsc.org
Organic xanthates are broadly applied as synthetic intermediates and bioactive molecules in
synthetic chemistry. Electrophilic xanthylation represents a promising approach but has …

Tandem SN2 Nucleophilic Substitution/Phospho-Dieckmann Reaction: One-Step Synthesis of 2-Phosphonyl-3-hydroxybenzo[b]thiophenes

Y Li, J Shen, Y Shen, Y Li, K Luo… - The Journal of Organic …, 2023 - ACS Publications
A novel and efficient tandem SN2 nucleophilic substitution/Dieckmann condensation
reaction of α-iodomethyl phosphine oxide with methyl thiosalicylate derivatives has been …

Direct dehydroxy (sulfhydryl) xanthylation of alcohols and thiols

D Shan, M Jiang, F Liang, Y Zhong… - Organic Chemistry …, 2024 - pubs.rsc.org
Alkyl xanthates are broadly applied as synthetic intermediates for expedient access to a
range of functional group derivatives in synthetic chemistry. Dehydroxyxanthylations of …

Cu-Catalyzed and iodine mediated synthesis of thioaurones via in situ C–S bond generation using xanthate as a sulfur surrogate

P Soundarya, G Sekar - Organic & Biomolecular Chemistry, 2022 - pubs.rsc.org
An efficient method for synthesizing thioaurones has been developed using xanthate as an
odorless sulfur surrogate. This reaction's key success lies in the use of iodine as a reagent …

KI/K2S2O8 Mediated Cascade C(sp3)−H/C(sp2)−H Thiolation for the Synthesis of Multi‐Substituted Thiazoles

L Liu, J Zhang - European Journal of Organic Chemistry, 2022 - Wiley Online Library
Thiazole and carbonyl often act as core functional or regulative moieties in biological
molecules as well as optical materials. Designing and synthesis of carbonyl‐containing …

Synthesis and Biological Evaluation of Thiophene and Its Derivatives

B Dam, BK Patel - S-Heterocycles: Synthesis and Biological Evaluation, 2024 - Springer
Sulfur-containing heterocycles are ever-trending core molecules in pharmaceutical
research. Derivatives of thiophene are a class of S-containing heterocycles that have been …

Chalcogen-based Probes

GS Malankar, BS Cugnasca, F Wodtke… - 2023 - books.rsc.org
Fluorescent sensors based on small organic molecules have been most widely developed
as sensors for monitoring in vitro and in vivo biological targets because of their simplicity …

Chalcogen-containing and Chalcogen-functionalized Heterocycles

F Penteado, E Alberto - 2023 - books.rsc.org
Heterocycles compose one of the most impressive classes of compounds, being widely
found in an extensive range of organisms where they exhibit several biochemical functions …