Exploration of Pynaphthyridine and Binaphthyridine Manganese (I) Tricarbonyl Complexes: Influence on Carbon Dioxide Reduction Electrocatalysis

KY Cohen, H Simonyan, M Ortiz, BF Solomon… - …, 2024 - ACS Publications
For CO2 electrocatalysts of the form fac-[Mn (diimine)(CO) 3Br], we previously reported that
expanding the π-system of the chelating ligand from 2, 2′-bipyridine (bpy) to 2-(2-pyridyl) …

Extending the π‐System in MnI Diimine Tricarbonyl Complexes: Impacts on Photochemistry, Electrochemistry, and CO2 Catalytic Reduction Activity

KY Cohen, R Evans, AB Bocarsly - European Journal of …, 2023 - Wiley Online Library
Abstract The complex [Mn (bpy)(CO) 3Br], has been previously studied as both an
electrocatalyst and a photocatalyst, in conjugation with a photosensitizer, for CO2 reduction …

Mechanistic insights of electrocatalytic CO 2 reduction by Mn complexes: synergistic effects of the ligands

H Sun, X Liu, Y Li, F Zhang, X Huang, C Sun… - Dalton …, 2024 - pubs.rsc.org
The electrocatalytic mechanisms of CO2 reduction catalyzed by pyridine-oxazoline (pyrox)-
based Mn catalysts were investigated by DFT calculations. In-depth comparative analyses of …

Manganese (I) Diamine Electrocatalysts: Electrochemical Carbon Dioxide Reduction to Carbon Monoxide

B Dhakal, BA Corbin, A Sosa Parada, JG Sakai… - Inorganics, 2023 - mdpi.com
Novel organometallic complexes Mn (benzene-1, 2-diamine)(CO) 3Br, Mn-1, Mn (3-
methylbenzene-1, 2-diamine)(CO) 3Br, Mn-2, and Re (benzene-1, 2-diamine)(CO) 3Cl, Re …

Mechanistic Insights into CO2 Photo-and Electroreduction Using Manganese Complexes

KY Cohen - 2024 - search.proquest.com
Photo-and electrochemical reduction is a promising approach to utilize carbon dioxide as a
chemical feedstock. To this end, complexes of the form, fac-[Mn (αdiimine)(CO) 3 Br] were …